Theoretical investigations on the stereoselective selenenylation reaction of alkenes
作者： Martin Spichty , Gianfranco Fragale , Thomas Wirth
DOI: 10.1021/JA001602L
关键词: Computational chemistry 、 Selectivity 、 Ab initio quantum chemistry methods 、 Stereoselectivity 、 Electrophile 、 Heteroatom 、 Reagent 、 Chemistry 、 Side chain 、 Organic chemistry 、 Selenium
摘要: Ab initio calculations have been performed to study the stereoselective selenenylation reaction of alkenes with chiral selenium electrophiles. The interaction heteroatom side chain atom in reagent has investigated by a detailed conformational analysis. Calculations seleniranium intermediates different substituted as well. reversal selectivity changing from aromatic aliphatic substrates already proven experiment and is now supported described herein.
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