Photo-anode surface modification using novel graphene oxide integrated with methylammonium lead iodide in organic-inorganic perovskite solar cells

作者: T. Stalin , J. Anandha Raj , Golap Kalita , Naushad Ahmad , Manawwer Alam

DOI: 10.1016/J.JPCS.2021.110036

关键词: PhotochemistryX-ray photoelectron spectroscopyEnergy conversion efficiencyMaterials scienceOxideMicroscopyGrapheneSurface modificationIodidePerovskite (structure)

摘要: Abstract The novel graphene oxide sheet-methylammonium lead iodide (GO-MAPbI3) was used as photoanode surface modification and is a photosensitizer for perovskite solar cells. multi-crystalline presence of GO-MAPbI3-prepared photo-anode morphologies were observed by high-resolution electron transmission microscopy scanning microscopy. selected diffraction pattern GO-MAPbI3 has also been in nature. containing the elementary composition determined using X-ray photoelectron spectroscopy. They consist Pb 4f5/2 4f7/2 have an energy binding value 143.9 (eV) 138.9 (eV). crystalline cubic black color confirmed pattern. From Fourier transform infrared spectra, functional groups, methylammonium internal hydrogen bonding between C–N group attached to C–H its corresponding values. photo-current density-voltage curves are regulated coated on giving 8.39% power conversion efficiency.

参考文章(72)
Yadnesh Kesari, Anjali Athawale, Ultrasound assisted bulk synthesis of CH3NH3PbI3 perovskite at room temperature Materials Letters. ,vol. 159, pp. 87- 89 ,(2015) , 10.1016/J.MATLET.2015.05.176
Like Huang, Ziyang Hu, Jie Xu, Ke Zhang, Jing Zhang, Yuejin Zhu, Multi-step slow annealing perovskite films for high performance planar perovskite solar cells Solar Energy Materials and Solar Cells. ,vol. 141, pp. 377- 382 ,(2015) , 10.1016/J.SOLMAT.2015.06.018
Yuichi Kato, Luis K. Ono, Michael V. Lee, Shenghao Wang, Sonia R. Raga, Yabing Qi, Silver Iodide Formation in Methyl Ammonium Lead Iodide Perovskite Solar Cells with Silver Top Electrodes Advanced Materials Interfaces. ,vol. 2, pp. 1500195- ,(2015) , 10.1002/ADMI.201500195
Tihong Wang, Yongfeng Li, Sai Geng, Chen Zhou, Xilai Jia, Fan Yang, Liqiang Zhang, Xiao Ren, Haitao Yang, Preparation of flexible reduced graphene oxide/poly(vinyl alcohol) film with superior microwave absorption properties RSC Advances. ,vol. 5, pp. 88958- 88964 ,(2015) , 10.1039/C5RA16158D
Xiaomei Chen, Genghuang Wu, Jinmei Chen, Xi Chen, Zhaoxiong Xie, Xiaoru Wang, Synthesis of "clean" and well-dispersive Pd nanoparticles with excellent electrocatalytic property on graphene oxide. Journal of the American Chemical Society. ,vol. 133, pp. 3693- 3695 ,(2011) , 10.1021/JA110313D
Shahid Ameer, Iftikhar Hussain Gul, Nasir Mahmood, Muhammad Mujahid, Semiconductor-to-metallic flipping in a ZnFe 2 O 4 –graphene based smart nano-system: Temperature/microwave magneto-dielectric spectroscopy Materials Characterization. ,vol. 99, pp. 254- 265 ,(2015) , 10.1016/J.MATCHAR.2014.11.018
Yingzhuang Ma, Lingling Zheng, Yao-Hsien Chung, Saisai Chu, Lixin Xiao, Zhijian Chen, Shufeng Wang, Bo Qu, Qihuang Gong, Zhaoxin Wu, Xun Hou, A highly efficient mesoscopic solar cell based on CH3NH3PbI3−xClx fabricated via sequential solution deposition Chemical Communications. ,vol. 50, pp. 12458- 12461 ,(2014) , 10.1039/C4CC01962H
Minlin Jiang, Jiamin Wu, Fei Lan, Quan Tao, Di Gao, Guangyong Li, Enhancing the performance of planar organo-lead halide perovskite solar cells by using a mixed halide source Journal of Materials Chemistry. ,vol. 3, pp. 963- 967 ,(2015) , 10.1039/C4TA05373G