Ultrathin high-resolution flexographic printing using nanoporous stamps

作者: Sanha Kim , Hossein Sojoudi , Hangbo Zhao , Dhanushkodi Mariappan , Gareth H. McKinley

DOI: 10.1126/SCIADV.1601660

关键词: Substrate (printing)NanoporousFlexographyCarbon nanotubeTransparent conducting filmRelief printingPrinted electronicsNanotechnologyMaterials scienceNanoparticle

摘要: Since its invention in ancient times, relief printing, commonly called flexography, has been used to mass-produce artifacts ranging from decorative graphics printed media. Now, higher-resolution flexography is essential manufacturing low-cost, large-area electronics. However, because of contact-mediated liquid instabilities and spreading, the resolution flexographic printing using elastomeric stamps limited tens micrometers. We introduce engineered nanoporous microstructures, comprising polymer-coated aligned carbon nanotubes (CNTs), as a next-generation stamp material. design engineer highly porous microstructures be wetted by colloidal inks transfer thin layer target substrate upon brief contact. demonstrate diverse micrometer-scale patterns variety functional nanoparticle inks, including Ag, ZnO, WO3, CdSe/ZnS, onto both rigid compliant substrates. The have uniform nanoscale thickness (5 50 nm) match features with high fidelity (edge roughness, ~0.2 μm). derive conditions for based on contact mechanics, characterize Ag lines transparent conductors, achieve continuous at speed 0.2 m/s. latter represents combination throughput that far surpasses industrial technologies.

参考文章(77)
Donald Lupo, Wolfgang Clemens, Sven Breitung, Klaus Hecker, OE-A Roadmap for Organic and Printed Electronics Applications of Organic and Printed Electronics. pp. 1- 26 ,(2013) , 10.1007/978-1-4614-3160-2_1
Won-Kyung Kim, Seunghun Lee, Duck Hee Lee, In Hee Park, Jong Seong Bae, Tae Woo Lee, Ji-Young Kim, Ji Hun Park, Yong Chan Cho, Chae Ryong Cho, Se-Young Jeong, Cu Mesh for Flexible Transparent Conductive Electrodes Scientific Reports. ,vol. 5, pp. 10715- 10715 ,(2015) , 10.1038/SREP10715
Bahram Rajabifar, Sanha Kim, Keith Slinker, Gregory J. Ehlert, A. John Hart, Matthew R. Maschmann, Three-dimensional machining of carbon nanotube forests using water-assisted scanning electron microscope processing Applied Physics Letters. ,vol. 107, pp. 143102- ,(2015) , 10.1063/1.4932522
James L. Wilbur, Amit Kumar, Enoch Kim, George M. Whitesides, Microfabrication by microcontact printing of self‐assembled monolayers Advanced Materials. ,vol. 6, pp. 600- 604 ,(1994) , 10.1002/ADMA.19940060719
Mostafa Bedewy, Eric R. Meshot, Haicheng Guo, Eric A. Verploegen, Wei Lu, A. John Hart, Collective mechanism for the evolution and self-termination of vertically aligned carbon nanotube growth Journal of Physical Chemistry C. ,vol. 113, pp. 20576- 20582 ,(2009) , 10.1021/JP904152V
Moon Kyu Kwak, Kyu Ho Shin, Eung Yeoul Yoon, Kahp Y. Suh, Fabrication of conductive metal lines by plate-to-roll pattern transfer utilizing edge dewetting and flexographic printing. Journal of Colloid and Interface Science. ,vol. 343, pp. 301- 305 ,(2010) , 10.1016/J.JCIS.2009.11.003
Malancha Gupta, Karen K. Gleason, Initiated Chemical Vapor Deposition of Poly(1H,1H,2H,2H-perfluorodecyl Acrylate) Thin Films Langmuir. ,vol. 22, pp. 10047- 10052 ,(2006) , 10.1021/LA061904M