Reaction Species in the Aqueous Solution and Interfacial Synthesis of Zirconium Polyethers
作者： Charles E. Carraher , Leonard M. Jambaya
DOI: 10.1080/00222337408068628
关键词: Aqueous solution 、 Zirconium 、 Yield (chemistry) 、 Chemistry 、 Organic layer 、 Phase (matter) 、 Diol 、 Base (chemistry) 、 Inorganic chemistry
摘要: Abstract The following tentative identifications are made from the study of variations in pH and substituted hydroquinones synthesis zirconium polyethers: active species for aqueous solution systems, CP2Zr2+ RO η interfacial Cp2 ZrCl2 R-OH with reaction occurring near interface or organic phase. Yield increases as stirring rate throughout range 13,000 to 24,500 rpm. Decent yields can also be obtained utilizing “inverse interfacial” systems where is originally contained water diol added base layer. No product found systems.
sci-hub.se 参考文章(9)
Charles E. Carraher, Synthesis and thermal analysis of hafnium polyesters Angewandte Makromolekulare Chemie. ,vol. 28, pp. 145- 151 ,(1973) , 10.1002/APMC.1973.050280112
Charles E. Carraher, Leonard M. Jambaya, Synthesis of zirconium polyethers Angewandte Makromolekulare Chemie. ,vol. 39, pp. 69- 76 ,(1974) , 10.1002/APMC.1974.050390106
F. Millich, C. E. Carraher, Interfacial syntheses of polyphosphonate and polyphosphate esters. I. Effects of alkaline medium Journal of Polymer Science Part A-1: Polymer Chemistry. ,vol. 7, pp. 2669- 2678 ,(1969) , 10.1002/POL.1969.150070916
Gerald Doyle, R. Stuart Tobias, Isolation of complex halo anions as the acetylacetonatobis(cyclopentadienyl)titanium(IV) and -vanadium(IV) salts. Reactions of bis(.pi.-cyclopentadienyl)titanium(IV) and bis(.pi.-cyclopentadienyl)vanadium(IV) with squarate and ethyl acetoacetate ions Inorganic Chemistry. ,vol. 7, pp. 2484- 2488 ,(1968) , 10.1021/IC50070A003
Charles Carraher, Reaction vessel with stirring and atmosphere controls Journal of Chemical Education. ,vol. 46, pp. 314- ,(1969) , 10.1021/ED046P314
Klaus Andräu, Über einige cyclische Wolfram- und Vanadinsäureester Zeitschrift für Chemie. ,vol. 7, pp. 318- 319 ,(2010) , 10.1002/ZFCH.19670070825
P. Ballinger, F. A. Long, Acid Ionization Constants of Alcohols. II. Acidities of Some Substituted Methanols and Related Compounds1,2 Journal of the American Chemical Society. ,vol. 82, pp. 795- 798 ,(1960) , 10.1021/JA01489A008
C.E. Carraher, S.T. Bajah, Synthesis of titanium polyethers by the interfacial and aqueous solution techniques Polymer. ,vol. 14, pp. 42- 44 ,(1973) , 10.1016/0032-3861(73)90093-1
Charles E. Carraher, Robert J. Nordin, Some reaction variables in the aqueous solution synthesis of titanium polythioethers Macromolecular Chemistry and Physics. ,vol. 164, pp. 87- 94 ,(1973) , 10.1002/MACP.1973.021640109