Kinetic and equilibrium studies of methylene blue biosorption by Posidonia oceanica (L.) fibres

作者: Mohamed Chaker Ncibi , Borhane Mahjoub , Mongi Seffen

DOI: 10.1016/J.JHAZMAT.2006.06.029

关键词: Nuclear chemistryBiosorptionLangmuirSorptionAdsorptionMethylene bluePosidonia oceanicaAqueous solutionChemistryChromatographyFreundlich equation

摘要: Batch biosorption experiments were carried out for the removal of methylene blue, a basic dye, from aqueous solution using raw Posidonia oceanica (L.) fibres, marine lignocellulosic biomass. A series assays undertaken to assess effect system variables, i.e. contact time, pH, biosorbent dosage and initial dye concentration. The results had showed that capacity was optimal 6-9 pH range by increasing concentration up 1 g/L. kinetics analyzed irreversible-first-order, reversible-first-order pseudo-second-order sorption data very well described model entire adsorption time with squared correlation coefficients equal unity all experimented concentrations. Besides, equilibrium represented both Langmuir Redlich-Peterson isotherm models followed Freundlich, which confirm monolayer coverage blue molecules onto P. fibres.

参考文章(22)
D KAVITHA, C NAMASIVAYAM, Experimental and kinetic studies on methylene blue adsorption by coir pith carbon. Bioresource Technology. ,vol. 98, pp. 14- 21 ,(2007) , 10.1016/J.BIORTECH.2005.12.008
Irving Langmuir, THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. Journal of the American Chemical Society. ,vol. 40, pp. 1361- 1403 ,(1918) , 10.1021/JA02242A004
Yuh-Shan Ho, Gordon McKay, SORPTION OF DYE FROM AQUEOUS SOLUTION BY PEAT Chemical Engineering Journal. ,vol. 70, pp. 115- 124 ,(1998) , 10.1016/S0923-0467(98)00076-1
P. Waranusantigul, P. Pokethitiyook, M. Kruatrachue, E.S. Upatham, Kinetics of basic dye (methylene blue) biosorption by giant duckweed (Spirodela polyrrhiza). Environmental Pollution. ,vol. 125, pp. 385- 392 ,(2003) , 10.1016/S0269-7491(03)00107-6
Borhane Mahjoub, Emmanuel Jayr, Rémy Bayard, Rémy Gourdon, Phase partition of organic pollutants between coal tar and water under variable experimental conditions Water Research. ,vol. 34, pp. 3551- 3560 ,(2000) , 10.1016/S0043-1354(00)00100-7
S Venkata Mohan, N Chandrasekhar Rao, J Karthikeyan, None, Adsorptive removal of direct azo dye from aqueous phase onto coal based sorbents: a kinetic and mechanistic study Journal of Hazardous Materials. ,vol. 90, pp. 189- 204 ,(2002) , 10.1016/S0304-3894(01)00348-X