Regio- and stereo-selective polymerization of 1,3-butadiene catalyzed by phosphorus–nitrogen PN3-pincer cobalt(II) complexes

作者: Dirong Gong , Xuequan Zhang , Kuo-Wei Huang

DOI: 10.1039/C6DT03722D

关键词: Trigonal bipyramidal molecular geometryMedicinal chemistryMoietyPyrazoleStereochemistryChemistryPolymerizationSelectivitySubstituentSteric effectsCobalt

摘要: A new family of cobalt complexes (CoCl2-H, CoCl2-Me, CoCl2-iPr, CoBr2-H, CoBr2-Me, CoBr2-iPr, CoI2-H, CoI2-Me, and CoI2-iPr) supported by a PN3 ligand (6-(N, N′-di-t …

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