Phase evolution, microstructure and microwave dielectric properties of 2Li2O-AO-3WO3 (A=Mg, Zn) composite ceramics

作者: Huanfu Zhou , Xianghu Tan , Jin Huang , Kangguo Wang , Wendong Sun

DOI: 10.1007/S10854-017-6939-X

关键词: SinteringPhase evolutionCeramicMicrostructureRelative permittivityMaterials scienceMicrowave dielectric propertiesComposite numberMetallurgyMicrowaveAnalytical chemistry

摘要: Low-firing microwave dielectric ceramics with compositions of 2Li2O-AO-3WO3 (A=Mg, Zn) were prepared by the solid state reaction method. The sintering behavior, microstructure and properties investigated. bulk density, quality factor (Q × f) relative permittivity (e r ) firstly increased, reached a max value then decreased increasing temperature. 2Li2O-MgO-3WO3 shown low temperature (~700 °C) good Q × f 23,582 GHz, e 5.89 τ f −78 ppm/°C. 2Li2O-ZnO-3WO3 sintered at 675 °C also presented excellent Q × f = 21,706 GHz,  = 6.76  = −94 ppm/°C. Most importantly, illustrated chemical compatiblity silver powders, which indicate that they can be used to LTCC multilayer devices.

参考文章(28)
Jianzhang Gong, Huanfu Zhou, Fen He, Xiuli Chen, Jie Chen, Liang Fang, Structural evolution, low-firing characteristic and microwave dielectric properties of magnesium and sodium vanadate ceramic Ceramics International. ,vol. 41, pp. 11125- 11131 ,(2015) , 10.1016/J.CERAMINT.2015.05.060
Mingwei Zhang, Jiwei Zhai, Jingji Zhang, Haitao Jiang, Xi Yao, Effect of MgWO4 content on properties of Ba0.5Sr0.5TiO3 composite ceramics for tunable microwave applications Materials Research Bulletin. ,vol. 46, pp. 1102- 1106 ,(2011) , 10.1016/J.MATERRESBULL.2011.02.046
Huiping Sun, Qilong Zhang, Hui Yang, Jiali Zou, (Ca1−xMgx)SiO3: A low-permittivity microwave dielectric ceramic system Materials Science and Engineering: B. ,vol. 138, pp. 46- 50 ,(2007) , 10.1016/J.MSEB.2007.01.012
Jianli Ma, Zhifen Fu, Peng Liu, Xudong Tang, Microwave dielectric properties of low-fired Li2ZrO3–ZnO composite ceramics Journal of Materials Science: Materials in Electronics. ,vol. 27, pp. 232- 236 ,(2016) , 10.1007/S10854-015-3744-2
Wen Lei, Wen-Zhong Lu, Xiao-Hong Wang, Fei Liang, Jun Wang, Phase Composition and Microwave Dielectric Properties of ZnAl2O4–Co2TiO4 Low‐Permittivity Ceramics with High Quality Factor Journal of the American Ceramic Society. ,vol. 94, pp. 20- 23 ,(2011) , 10.1111/J.1551-2916.2010.04247.X
Kecheng Li, Hong Wang, Huanfu Zhou, Minghui Zhang, Xi Yao, Silver Co‐Firable ZnTiNb2O8 Microwave Dielectric Ceramics with Li2O–ZnO–B2O3 Glass Additive International Journal of Applied Ceramic Technology. ,vol. 7, ,(2010) , 10.1111/J.1744-7402.2009.02475.X
Wei Wang, Wangfeng Bai, Bo Shen, Jiwei Zhai, Microwave dielectric properties of low temperature sintered ZnWO4–TiO2 composite ceramics Ceramics International. ,vol. 41, ,(2015) , 10.1016/J.CERAMINT.2015.03.122
T Lowe, F Azough, R Freer, The microwave dielectric properties of CaTiO3–Li0.5Nd0.5TiO3 ceramics prepared with Bi2Ti2O7 additions Journal of The European Ceramic Society. ,vol. 23, pp. 2429- 2433 ,(2003) , 10.1016/S0955-2219(03)00131-6