Elastic properties of bimesogenic liquid crystals

作者: R. Balachandran , V.P. Panov , J.K. Vij , A. Kocot , M.G. Tamba

DOI: 10.1080/02678292.2013.765973

关键词: MoleculePhase (matter)DimerDielectric permittivityMaterials scienceConstant (mathematics)Condensed matter physicsLiquid crystalOptics

摘要: The second nematic phase found in some bimesogenic liquid crystals with an odd flexible spacer has aroused considerable interest due to many unusual properties exhibited by them. However, the reason for such molecules exhibit transitions modulated is still unclear. Dozov [Europhys Lett. 2001;56:247] predicted that negative K 33 can lead a where director either splay-bend or twist-bend distribution. Though various theoretical studies have suggested this scenario may be valid, no experimental evidence so far been given. In order study influence of elastic constants, we measured splay and bend constants ordinary dimer material, CBC11CB, temperatures down 0.6°C above Nx–Nu transition. Our results show constant reduced factor 2 compared closer I-Nu transition but positive trend does not seem will extrapolate zero fall below it t...

参考文章(28)
D. Demus, J. Goodby, G. W. Gray, H.‐W. Spiess, V. Vill, Handbook of liquid crystals Wiley-VCH Verlag GmbH. ,(1998) , 10.1002/9783527620555
V. P. Panov, R. Balachandran, J. K. Vij, M. G. Tamba, A. Kohlmeier, G. H. Mehl, Field-induced periodic chiral pattern in the Nx phase of achiral bimesogens Applied Physics Letters. ,vol. 101, pp. 234106- ,(2012) , 10.1063/1.4769458
H. J. Coles, M. J. Clarke, S. M. Morris, B. J. Broughton, A. E. Blatch, Strong flexoelectric behavior in bimesogenic liquid crystals Journal of Applied Physics. ,vol. 99, pp. 034104- ,(2006) , 10.1063/1.2166643
P. Sathyanarayana, B. K. Sadashiva, Surajit Dhara, Splay-bend elasticity and rotational viscosity of liquid crystal mixtures of rod-like and bent-core molecules Soft Matter. ,vol. 7, pp. 8556- 8560 ,(2011) , 10.1039/C1SM05751K
F. Castles, S. M. Morris, E. M. Terentjev, H. J. Coles, Thermodynamically stable blue phases. Physical Review Letters. ,vol. 104, pp. 157801- ,(2010) , 10.1103/PHYSREVLETT.104.157801
Peter A. Henderson, Corrie T. Imrie, Methylene-linked liquid crystal dimers and the twist-bend nematic phase Liquid Crystals. ,vol. 38, pp. 1407- 1414 ,(2011) , 10.1080/02678292.2011.624368
S Kaur, J Addis, Cristina Greco, Alberta Ferrarini, V Görtz, JW Goodby, HF Gleeson, None, Understanding the distinctive elastic constants in an oxadiazole bent-core nematic liquid crystal Physical Review E. ,vol. 86, pp. 041703- 041703 ,(2012) , 10.1103/PHYSREVE.86.041703
Mirko Cestari, Elisa Frezza, Alberta Ferrarini, Geoffrey R. Luckhurst, Crucial role of molecular curvature for the bend elastic and flexoelectric properties of liquid crystals: mesogenic dimers as a case study Journal of Materials Chemistry. ,vol. 21, pp. 12303- 12308 ,(2011) , 10.1039/C1JM12233A