Performance enhancement of dye-sensitized solar cells based on anthocyanin by carbohydrates
作者： Chiang-Yu Chien , Ban-Dar Hsu
DOI: 10.1016/J.SOLENER.2014.08.009
关键词: Xylooligosaccharide 、 Energy conversion efficiency 、 Dye-sensitized solar cell 、 Performance enhancement 、 Anthocyanin 、 Nuclear chemistry 、 Chemistry 、 Deoxycholic acid 、 Red cabbage
摘要: Abstract Dye-sensitized solar cells (DSSCs) were fabricated using anthocyanin extracted from red cabbage ( Brassica oleracea var. capitata f. rubra ). Carbohydrates found to be excellent performance enhancers that functioned in a dose-dependent manner. Different types of carbohydrates generally had different enhancement capabilities the order oligosaccharide > disaccharide > monosaccharide > polysaccharide. The capability was also highly dependent on constituents carbohydrates. Two oligosaccharides, Isomalto-oligosaccharide (IMO) and xylooligosaccharide (XOS), showed highest capability. DSSCs sensitized with them as additives exhibited power conversion efficiency η ) over 1.6% (an improvement 60%) short-circuit current J SC about 4 mA/cm 2 , open-circuit voltage V OC around 630 mV. mode interaction extrinsic proposed discussed. use common coadsorbent deoxycholic acid (DCA) together could induce an additional enhancement, which boosted up 1.87% accumulative 90%). This study provided choice promising powerful enhancer for based natural anthocyanins.
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sci-hub.se 参考文章(41)
Stanley R. Benedict, A Reagent for the Detection of Reducing Sugars Journal of Biological Chemistry. ,vol. 5, pp. 485- 487 ,(1909) , 10.1016/S0021-9258(18)91645-5
C. Gaiddon, P. Jeannequin, P. Bischoff, M. Pfeffer, C. Sirlin, J. P. Loeffler, Ruthenium (II)-Derived Organometallic Compounds Induce Cytostatic and Cytotoxic Effects on Mammalian Cancer Cell Lines through p53-Dependent and p53-Independent Mechanisms Journal of Pharmacology and Experimental Therapeutics. ,vol. 315, pp. 1403- 1411 ,(2005) , 10.1124/JPET.105.089342
Raymond Brouillard, The in vivo expression of anthocyanin colour in plants Phytochemistry. ,vol. 22, pp. 1311- 1323 ,(1983) , 10.1016/S0031-9422(00)84008-X
Yuancheng Qin, Qiang Peng, Ruthenium Sensitizers and Their Applications in Dye-Sensitized Solar Cells International Journal of Photoenergy. ,vol. 2012, pp. 1- 21 ,(2012) , 10.1155/2012/291579
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Mohammad K. Nazeeruddin, Peter Péchy, Thierry Renouard, Shaik M. Zakeeruddin, Robin Humphry-Baker, Pascal Comte, Paul Liska, Le Cevey, Emiliana Costa, Valery Shklover, Leone Spiccia, Glen B. Deacon, Carlo A. Bignozzi, Michael Grätzel, Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO2-Based Solar Cells Journal of the American Chemical Society. ,vol. 123, pp. 1613- 1624 ,(2001) , 10.1021/JA003299U
G.R.A. Kumara, S. Kaneko, M. Okuya, B. Onwona-Agyeman, A. Konno, K. Tennakone, Shiso leaf pigments for dye-sensitized solid-state solar cell Solar Energy Materials and Solar Cells. ,vol. 90, pp. 1220- 1226 ,(2006) , 10.1016/J.SOLMAT.2005.07.007
Sancun Hao, Jihuai Wu, Yunfang Huang, Jianming Lin, Natural dyes as photosensitizers for dye-sensitized solar cell Solar Energy. ,vol. 80, pp. 209- 214 ,(2006) , 10.1016/J.SOLENER.2005.05.009
Yasuo Chiba, Ashraful Islam, Yuki Watanabe, Ryoichi Komiya, Naoki Koide, Liyuan Han, Dye-Sensitized Solar Cells with Conversion Efficiency of 11.1% Japanese Journal of Applied Physics. ,vol. 45, pp. L638- L640 ,(2006) , 10.1143/JJAP.45.L638
Dorothe Spillmann, Max M. Burger, Carbohydrate-carbohydrate interactions in adhesion Journal of Cellular Biochemistry. ,vol. 61, pp. 562- 568 ,(1996) , 10.1002/(SICI)1097-4644(19960616)61:4<562::AID-JCB9>3.0.CO;2-M