Structure and ion transport behavior analysis of ionic liquid analogues based on magnesium chloride

作者: Duyuan Yue , Yan Jing , Jinhe Sun , Xiaohua Wang , Yongzhong Jia

DOI: 10.1016/J.MOLLIQ.2010.11.005

关键词: IonInorganic chemistryIon transporterSurface tensionConductivityMagnesiumChemistryIonic liquidCholine chlorideThermal analysisPhysical and Theoretical ChemistrySpectroscopyMaterials ChemistryAtomic and Molecular Physics, and OpticsElectronic, Optical and Magnetic MaterialsCondensed matter physics

摘要: Abstract A homogeneous, colorless ionic liquid analogue based on magnesium chloride and choline is reported. The structure of the analogues preliminarily investigated by FTIR. main chemical groups are confirmed interactions between different analyzed. Thermal analysis shows that stable from room temperature to 120 °C. physical properties such as viscosity, surface tension conductivity measured function compositions. ion transport behaviors analyzed using hole-theory. It shown controlled mobility suitable voids.

参考文章(28)
Electrodeposition from Ionic Liquids Wiley-VCH Verlag GmbH & Co. KGaA. ,(2008) , 10.1002/9783527622917
Takuma KATASE, Toshitake ONISHI, Susumu IMASHUKU, Kuniaki MURASE, Tetsuji HIRATO, Yasuhiro AWAKURA, Water content and properties of aliphatic ammonium imide-type room temperature ionic, liquid containing metal ions Electrochemistry. ,vol. 73, pp. 686- 691 ,(2005) , 10.5796/ELECTROCHEMISTRY.73.686
George Law, Philip R. Watson, Surface Tension Measurements of N-Alkylimidazolium Ionic Liquids Langmuir. ,vol. 17, pp. 6138- 6141 ,(2001) , 10.1021/LA010629V
Nobuko Yoshimoto, Takahiro Shirai, Masayuki Morita, A novel polymeric gel electrolyte systems containing magnesium salt with ionic liquid Electrochimica Acta. ,vol. 50, pp. 3866- 3871 ,(2005) , 10.1016/J.ELECTACTA.2005.02.036
Ratthaya Lertlapwasin, Nakara Bhawawet, Apichat Imyim, Saowarux Fuangswasdi, Ionic liquid extraction of heavy metal ions by 2-aminothiophenol in 1-butyl-3-methylimidazolium hexafluorophosphate and their association constants Separation and Purification Technology. ,vol. 72, pp. 70- 76 ,(2010) , 10.1016/J.SEPPUR.2010.01.004
Tao LONG, Yuefeng DENG, Shucai GAN, Ji CHEN, Application of Choline Chloride·xZnCl2 Ionic Liquids for Preparation of Biodiesel Chinese Journal of Chemical Engineering. ,vol. 18, pp. 322- 327 ,(2010) , 10.1016/S1004-9541(08)60359-6
Andrew P. Abbott, Robert C. Harris, Karl S. Ryder, Application of hole theory to define ionic liquids by their transport properties. Journal of Physical Chemistry B. ,vol. 111, pp. 4910- 4913 ,(2007) , 10.1021/JP0671998
Andrew P. Abbott, David J. Schiffrin, Conductivity of tetra-alkylammonium salts in polyaromatic solvents Journal of the Chemical Society, Faraday Transactions. ,vol. 86, pp. 1453- 1459 ,(1990) , 10.1039/FT9908601453
W. Sawodny, K. Niedenzu, J.W. Dawson, The vibrational spectrum of ethylene glycol Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 23, pp. 799- 806 ,(1967) , 10.1016/0584-8539(67)80007-2
A.P. Abbott, G. Capper, B.G. Swain, D.A. Wheeler, Electropolishing of stainless steel in an ionic liquid Transactions of The Institute of Metal Finishing. ,vol. 83, pp. 51- 53 ,(2005) , 10.1179/002029605X17657