Solvent effects in the electron spin resonance spectra of nitric oxide radicals and para-substituted nitrobenzene anions
作者： J. Pannell
DOI: 10.1080/00268976300101091
关键词: Solvent 、 Inorganic chemistry 、 Peroxide 、 Nitrobenzene 、 Equilibrium constant 、 Nitric oxide 、 Solvent effects 、 Nitrogen 、 Chemistry 、 Photochemistry 、 Radical
摘要: It is shown that the nitrogen hyperfine coupling parameters for nitric oxide radicals depend on solvent. An equilibrium constant calculated interaction of diphenyl and p-p′-dianisyl with di-tert-butyl peroxide tert-butyl hydroperoxide in a mixture two solvents. By plotting splitting found against series straight line obtained tentative theoretical treatment given to account this based equation Karplus Fraenkel. Similar results are hold para-substituted nitrobenzene anions.
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