23Na-NMR Study in NaV6O11

作者: Harukazu Kato , Masaki Kato , Kazuyoshi Yoshimura , Koji Kosuge

DOI: 10.1143/JPSJ.70.1404

关键词: Ground stateMagnetic susceptibilityCondensed matter physicsPhysicsSpin–lattice relaxationVanadiumIonGeometrical frustrationCrystallographyKnight shiftFrustration

摘要: A mixed valent vanadium compound NaV 6 O 11 shows a magnetic phase transition at T t =245 K. For the microscopic investigation of , 23 Na-NMR measurements from 70 K to 300 were carried out on . The Knight shift, and nuclear spin-lattice relaxation rate, 1/ 1 measured. While above has an almost constant value, below gap-type temperature dependence. This is first direct evidence that d -electrons V(1) ions, which form kagome lattice in exhibit spin-singlet ground state formation seems be closely related frustration effect.

参考文章(21)
Yoshishige Uchida, Yasushi Kanke, Eiji Takayama-Muromachi, Katsuo Kato, Magnetic Properties of NaV6O11 Journal of the Physical Society of Japan. ,vol. 60, pp. 2530- 2533 ,(1991) , 10.1143/JPSJ.60.2530
Y. J. Uemura, A. Keren, K. Kojima, L. P. Le, G. M. Luke, W. D. Wu, Y. Ajiro, T. Asano, Y. Kuriyama, M. Mekata, H. Kikuchi, K. Kakurai, Spin fluctuations in frustrated kagomé lattice system SrCr8Ga4O19 studied by muon spin relaxation. Physical Review Letters. ,vol. 73, pp. 3306- 3309 ,(1994) , 10.1103/PHYSREVLETT.73.3306
Nobuo Wada, Tatsuya Kobayashi, Hideo Yano, Tsunehisa Okuno, Akira Yamaguchi, Kunio Awaga, Observation of Spin-Gap State in Two-Dimensional Spin-1 Kagomé Antiferromagnet m-MPYNN·BF4 Journal of the Physical Society of Japan. ,vol. 66, pp. 961- 964 ,(1997) , 10.1143/JPSJ.66.961
A. P. Ramirez, B. Hessen, M. Winklemann, Entropy balance and evidence for local spin singlets in a Kagome-like magnet Physical Review Letters. ,vol. 84, pp. 2957- 2960 ,(2000) , 10.1103/PHYSREVLETT.84.2957
M.E. de Roy, J.P. Besse, R. Chevalier, M. Gasperin, Synthèse et structure cristalline de NaV6O11 Journal of Solid State Chemistry. ,vol. 67, pp. 185- 189 ,(1987) , 10.1016/0022-4596(87)90353-7
Y. Kanke, E. Takayama-Muromachi, K. Kato, Y. Matsui, Phase equilibrium study of the system NaV2O5V2O3V2O5 at 923 K Journal of Solid State Chemistry. ,vol. 89, pp. 130- 137 ,(1990) , 10.1016/0022-4596(90)90302-E
P. W. Leung, Veit Elser, Numerical studies of a 36-site kagomé antiferromagnet Physical Review B. ,vol. 47, pp. 5459- 5462 ,(1993) , 10.1103/PHYSREVB.47.5459