UTILIZATION OF EGGSHELL-DERIVED MATERIAL AS A SOLID BASE CATALYST FOR EFFICIENT SYNTHESIS OF SUBSTITUTED CHALCONES
作者： Lina Mardiana , Bayu Ardiansah , Ridla Bakri , Antonius Herry Cahyana , Yulia Anita
关键词: Chalcone 、 Fourier transform infrared spectroscopy 、 Organic chemistry 、 Chemistry 、 Yield (chemistry) 、 Catalysis 、 Ethanol 、 Solvent 、 Aldol condensation 、 Sodium
摘要: A simple preparation of sodium impregnated on activated chicken eggshells (Na-ACE) as a solid base material for substituted chalcones synthesis is presented. After characterization using FTIR, XRD, SEM, EDS and total basicity, the catalyst was applied in Aldol condensation to produce corresponding 3a-3j. Confirmation products structure has been done by UV-Vis MS instruments. Reaction can be carried out relative short time with ethanol best solvent gave highest yield 95 %. This research presented facile chalcone derivatives, prominent class organic compounds interesting biological activities.
sci-hub.se 参考文章(31)
Saadia Leeza Zaidi, Sonam Mittal, Maitreyi S. Rajala, Fernando Avecilla, Mohammad Husain, Amir Azam, Synthesis, characterization and antiamoebic activity of chalcones bearing N-substituted ethanamine tail. European Journal of Medicinal Chemistry. ,vol. 98, pp. 179- 189 ,(2015) , 10.1016/J.EJMECH.2015.05.013
Gourishankar Karoshi, Praveen Kolar, Sanjay B. Shah, Gary Gilleskie, Lalitendu Das, Calcined eggshell as an inexpensive catalyst for partial oxidation of methane Journal of The Taiwan Institute of Chemical Engineers. ,vol. 57, pp. 123- 128 ,(2015) , 10.1016/J.JTICE.2015.05.025
Yie Hua Tan, Mohammad Omar Abdullah, Cirilo Nolasco-Hipolito, Yun Hin Taufiq-Yap, Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: Catalyst characterization and biodiesel yield performance Applied Energy. ,vol. 160, pp. 58- 70 ,(2015) , 10.1016/J.APENERGY.2015.09.023
Dinesh Kumar, Amjad Ali, None, Nanocrystalline K–CaO for the transesterification of a variety of feedstocks: Structure, kinetics and catalytic properties Biomass & Bioenergy. ,vol. 46, pp. 459- 468 ,(2012) , 10.1016/J.BIOMBIOE.2012.06.040
Roberto Ballini, Giovanna Bosica, Massimo Ricciutelli, Raimondo Maggi, Giovanni Sartori, Raffaella Sartorio, Paolo Righi, Clay-catalysed solventless synthesis of trans-chalcones Green Chemistry. ,vol. 3, pp. 178- 180 ,(2001) , 10.1039/B101355F
Xuan Fu, Juhua Feng, Zhenhua Dong, Lili Lin, Xiaohua Liu, Xiaoming Feng, Enantioselective Synthesis of 2-Substituted-1,5-Benzodiazepines through Domino Reaction of o-Phenylenediamine and Chalcone Derivatives European Journal of Organic Chemistry. ,vol. 2011, pp. 5233- 5236 ,(2011) , 10.1002/EJOC.201100938
Maedeh Mohammadi, Pooya Lahijani, Abdul Rahman Mohamed, Refractory dopant-incorporated CaO from waste eggshell as sustainable sorbent for CO2 capture: Experimental and kinetic studies Chemical Engineering Journal. ,vol. 243, pp. 455- 464 ,(2014) , 10.1016/J.CEJ.2014.01.018
Lalita B. Kunde, Swapna M. Gade, Vishwanath S. Kalyani, Sunil P. Gupte, Catalytic synthesis of chalcone and flavanone using Zn–Al hydrotalcite adhere ionic liquid Catalysis Communications. ,vol. 10, pp. 1881- 1888 ,(2009) , 10.1016/J.CATCOM.2009.06.018
Danlin Zeng, Qi Zhang, Shiyuan Chen, Shenglan Liu, Yang Chen, Yongsheng Tian, Guanghui Wang, Preparation and characterization of a strong solid base from waste eggshell for biodiesel production Journal of environmental chemical engineering. ,vol. 3, pp. 560- 564 ,(2015) , 10.1016/J.JECE.2015.01.014
Keke Hu, Huajun Wang, Yihua Liu, Chao Yang, KNO3/CaO as cost-effective heterogeneous catalyst for the synthesis of glycerol carbonate from glycerol and dimethyl carbonate Journal of Industrial and Engineering Chemistry. ,vol. 28, pp. 334- 343 ,(2015) , 10.1016/J.JIEC.2015.03.012