Degradation of flumequine by photocatalysis and evaluation of antimicrobial activity
作者： Caio Rodrigues-Silva , Milena Guedes Maniero , Susanne Rath , José Roberto Guimarães
DOI: 10.1016/J.CEJ.2012.11.002
关键词: Veterinary drug 、 Mass spectrometry 、 Catalysis 、 Flumequine 、 Photocatalysis 、 Degradation (geology) 、 Pollutant 、 Antimicrobial 、 Chromatography 、 Chemistry
摘要: Abstract This study evaluated the efficiencies of advanced oxidation processes (UV/TiO2 and UV/TiO2/H2O2) for flumequine degradation, an antimicrobial emergent pollutant. The photocatalytic process was capable degrading approximately 55% drug after 15 min reaction using 0.31 mmol L−1 TiO2 in suspension; addition H2O2 (0.5 mmol L−1) increased degradation to 81.6%. For UV/TiO2, increasing catalyst concentration (0.08–0.62 mmol L−1) corresponded increase efficiency. Using mass spectrometry, it possible identify five putative byproducts formed during processes. Due risks bacterial resistance, activity treated solutions compared untreated solution. Residual detected all conditions. considerably reduced by throughout reaction.
sci-hub.se 参考文章(35)
Hyun-Seok Son, Gwangpyo Ko, Kyung-Duk Zoh, Kinetics and mechanism of photolysis and TiO2 photocatalysis of triclosan Journal of Hazardous Materials. ,vol. 166, pp. 954- 960 ,(2009) , 10.1016/J.JHAZMAT.2008.11.107
J. Nieto, J. Freer, D. Contreras, R.J. Candal, E.E. Sileo, H.D. Mansilla, Photocatalyzed degradation of flumequine by doped TiO2 and simulated solar light. Journal of Hazardous Materials. ,vol. 155, pp. 45- 50 ,(2008) , 10.1016/J.JHAZMAT.2007.11.026
Carla Sirtori, Ana Zapata, Sixto Malato, Wolfgang Gernjak, Amadeo R. Fernández-Alba, Ana Agüera, Solar photocatalytic treatment of quinolones: intermediates and toxicity evaluation Photochemical and Photobiological Sciences. ,vol. 8, pp. 644- 651 ,(2009) , 10.1039/B817247A
H.D. Mansilla, A. Mora, C. Pincheira, M.A. Mondaca, P.D. Marcato, N. Durán, J. Freer, New photocatalytic reactor with TiO2 coating on sintered glass cylinders Applied Catalysis B-environmental. ,vol. 76, pp. 57- 63 ,(2007) , 10.1016/J.APCATB.2007.04.025
Fatima Tamtam, Fabien Mercier, Barbara Le Bot, Joëlle Eurin, Quoc Tuc Dinh, Michel Clément, Marc Chevreuil, Occurrence and fate of antibiotics in the Seine River in various hydrological conditions Science of The Total Environment. ,vol. 393, pp. 84- 95 ,(2008) , 10.1016/J.SCITOTENV.2007.12.009
Tias Paul, Penney L. Miller, Timothy J. Strathmann, Visible-Light-Mediated TiO2 Photocatalysis of Fluoroquinolone Antibacterial Agents Environmental Science & Technology. ,vol. 41, pp. 4720- 4727 ,(2007) , 10.1021/ES070097Q
Tusnelda E. Doll, Fritz H. Frimmel, REMOVAL OF SELECTED PERSISTENT ORGANIC POLLUTANTS BY HETEROGENEOUS PHOTOCATALYSIS IN WATER Catalysis Today. ,vol. 101, pp. 195- 202 ,(2005) , 10.1016/J.CATTOD.2005.03.005
Roberta Galarini, Laura Fioroni, Federico Angelucci, Gloria R. Tovo, Elisa Cristofani, Simultaneous determination of eleven quinolones in animal feed by liquid chromatography with fluorescence and ultraviolet absorbance detection Journal of Chromatography A. ,vol. 1216, pp. 8158- 8164 ,(2009) , 10.1016/J.CHROMA.2009.06.076
Zhengqi Ye, Howard S. Weinberg, Michael T. Meyer, Trace analysis of trimethoprim and sulfonamide, macrolide, quinolone, and tetracycline antibiotics in chlorinated drinking water using liquid chromatography electrospray tandem mass spectrometry. Analytical Chemistry. ,vol. 79, pp. 1135- 1144 ,(2007) , 10.1021/AC060972A
Patrick K. Jjemba, Excretion and ecotoxicity of pharmaceutical and personal care products in the environment. Ecotoxicology and Environmental Safety. ,vol. 63, pp. 113- 130 ,(2006) , 10.1016/J.ECOENV.2004.11.011