Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant.

作者: Peng Li , Rachel C. Klet , Su-Young Moon , Timothy C. Wang , Pravas Deria

DOI: 10.1039/C5CC03398E

关键词: Catalytic hydrolysisCrystalliteDegradation (geology)NanocrystalStereochemistryMaterials scienceMetal-organic frameworkNerve agentParaoxonChemical engineering

摘要: … 11a,22 Our group has investigated the catalytic activity of several MOFs with Zr 6 … 1). While UiO-66 and UiO-67 feature 12-connected Zr 6 nodes, NU-1000 presents 8-connected Zr 6 …

参考文章(59)
Omar K. Farha, A. Özgür Yazaydın, Ibrahim Eryazici, Christos D. Malliakas, Brad G. Hauser, Mercouri G. Kanatzidis, SonBinh T. Nguyen, Randall Q. Snurr, Joseph T. Hupp, De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Nature Chemistry. ,vol. 2, pp. 944- 948 ,(2010) , 10.1038/NCHEM.834
A. Corma, H. García, F. X. Llabrés i Xamena, Engineering Metal Organic Frameworks for Heterogeneous Catalysis Chemical Reviews. ,vol. 110, pp. 4606- 4655 ,(2010) , 10.1021/CR9003924
William J. Rieter, Kathryn M. L. Taylor, Hongyu An, Weili Lin, Wenbin Lin, Nanoscale metal-organic frameworks as potential multimodal contrast enhancing agents. Journal of the American Chemical Society. ,vol. 128, pp. 9024- 9025 ,(2006) , 10.1021/JA0627444
William Morris, Boris Volosskiy, Selcuk Demir, Felipe Gándara, Psaras L. McGrier, Hiroyasu Furukawa, Duilio Cascio, J. Fraser Stoddart, Omar M. Yaghi, Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal-Organic Frameworks Inorganic Chemistry. ,vol. 51, pp. 6443- 6445 ,(2012) , 10.1021/IC300825S
Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp, SonBinh T. Nguyen, A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts Journal of the American Chemical Society. ,vol. 131, pp. 4204- 4205 ,(2009) , 10.1021/JA900203F
Banglin Chen, Shengchang Xiang, Guodong Qian, Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules Accounts of Chemical Research. ,vol. 43, pp. 1115- 1124 ,(2010) , 10.1021/AR100023Y
Chung-Wei Kung, Timothy Chiaan Wang, Joseph E. Mondloch, David Fairen-Jimenez, Daniel M. Gardner, Wojciech Bury, Jordan Matthew Klingsporn, Jonathan C. Barnes, Richard Van Duyne, J. Fraser Stoddart, Michael R. Wasielewski, Omar K. Farha, Joseph T. Hupp, Metal-organic framework thin films composed of free-standing acicular nanorods exhibiting reversible electrochromism Chemistry of Materials. ,vol. 25, pp. 5012- 5017 ,(2013) , 10.1021/CM403726V
Lifang Song, Jian Zhang, Lixian Sun, Fen Xu, Fen Li, Huanzhi Zhang, Xiaoliang Si, Chengli Jiao, Zhibao Li, Shuang Liu, Yingliang Liu, Huaiying Zhou, Dalin Sun, Yong Du, Zhong Cao, Zelimir Gabelica, Mesoporous metal-organic frameworks: design and applications Energy and Environmental Science. ,vol. 5, pp. 7508- 7520 ,(2012) , 10.1039/C2EE03517K
Nazmul Abedin Khan, In Joong Kang, Hwi Young Seok, Sung Hwa Jhung, Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101 Chemical Engineering Journal. ,vol. 166, pp. 1152- 1157 ,(2011) , 10.1016/J.CEJ.2010.11.098
Xiaoxia Li, Fangyi Cheng, Shuna Zhang, Jun Chen, Shape-controlled synthesis and lithium-storage study of metal-organic frameworks Zn4O(1,3,5-benzenetribenzoate)2 Journal of Power Sources. ,vol. 160, pp. 542- 547 ,(2006) , 10.1016/J.JPOWSOUR.2006.01.015