Composite thin films of (ZrO2)x-(Al2O3)1−x for high transmittance attenuated phase shifting mask in ArF optical lithography

作者: Fu-Der Lai

DOI: 10.1116/1.1701850

关键词: Thin filmTransmittanceSputter depositionAmorphous solidPhotolithographyMaterials scienceOpticsComposite numberOptoelectronicsCarbon filmVolume fraction

摘要: Stoichiometric (ZrO2)x-(Al2O3)1−x composite thin films are obtained by using rf unbalanced magnetron sputtering in an atmosphere of argon and oxygen. All the deposited amorphous. The ZrO2-Al2O3 will be nearly completely oxidized when O2/Ar flow rate ratio exceeds 0.5. optical constants calculated measured. measured values agree well with ones applying Hunderi effective medium model. can tuned controlling volume fraction ZrO2 Al2O3 films. requirements for a high-transmission attenuated phase-shifting mask (HT-APSM) blank satisfied suitable choice fraction. An optimized ArF lithography transmittance value 18%–20%, which conforms to typical HT-APSM blank, realized range 54.8% 48.8%. To used as one π-phase-shifted film...

参考文章(23)
Erhard Dorre, E. Dörre, H. Hübner, Alumina: Processing, Properties, and Applications ,(1984)
Melvin M Schwartz, Composite Materials Handbook ,(1984)
Ola Hunderi, The optical properties of thin films and superlattices Physica A-statistical Mechanics and Its Applications. ,vol. 157, pp. 309- 322 ,(1989) , 10.1016/0378-4371(89)90317-8
A. Feldman, E. N. Farabaugh, W. K. Haller, D. M. Sanders, R. A. Stempniak, Modifying structure and properties of optical films by coevaporation Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. ,vol. 4, pp. 2969- 2974 ,(1986) , 10.1116/1.573610
William J. Gunning, Randolph L. Hall, Frank J. Woodberry, W. H. Southwell, Natalie S. Gluck, Codeposition of continuous composition rugate filters. Applied Optics. ,vol. 28, pp. 2945- 2948 ,(1989) , 10.1364/AO.28.002945
B. J. Pond, J. I. DeBar, C. K. Carniglia, T. Raj, Stress reduction in ion beam sputtered mixed oxide films Applied Optics. ,vol. 28, pp. 2800- 2805 ,(1989) , 10.1364/AO.28.002800
Peter F Carcia, Roger H French, Kenneth G Sharp, Jeff S Meth, Bruce W Smith, None, Materials Screening for Attenuating Embedded {Phase-Shift} Photoblanks for {DUV} and 193 nm Photolithography 16th Annual BACUS Symposium on Photomask Technology and Management. ,vol. 2884, pp. 255- 263 ,(1996) , 10.1117/12.262809
Tadashi Matsuo, Kinji Ohkubo, Takashi Haraguchi, Kohsuke Ueyama, Zr-based films for attenuated phase-shift mask Photomask and X-Ray Mask Technology IV. ,vol. 3096, pp. 354- 361 ,(1997) , 10.1117/12.277280
N. S. Gluck, H. Sankur, J. Heuer, J. DeNatale, W. J. Gunning, Microstructure and composition of composite SiO2/TiO2 thin films Journal of Applied Physics. ,vol. 69, pp. 3037- 3045 ,(1991) , 10.1063/1.348591