Factors affecting the infra-red spectra of some planar anions with D3h symmetry—III. The spectra of rare-earth carbonates and their thermal decomposition products

作者: J.A. Goldsmith , S.D. Ross

DOI: 10.1016/0584-8539(67)80073-4

关键词: Physical chemistryChemistryRare earthPlanarInfraredInorganic chemistrySymmetry (physics)Potassium bromideThermal decompositionAnhydrousSpectral line

摘要: Abstract The infra-red spectra of the anhydrous and octahydrated rare-earth carbonates have been recorded as potassium bromide disks in region 4000–250 cm−1 are discussed light known crystallographic evidence for their structures. products formed by heating to 470°C were similarly an attempt find out if either monoxydicarbonate or dioxymonocarbonate formed. sesquioxides also reported.

参考文章(5)
J.A. Goldsmith, S.D. Ross, Factors affecting the infra-red spectra of planar anions with D3h symmetry—II The intensity of ν1 in some simple, basic and complex carbonates Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 22, pp. 1069- 1072 ,(1966) , 10.1016/0371-1951(66)80196-0
R.L.N. Sastry, S.R. Yoganarasimhan, P.N. Mehrotra, C.N.R. Rao, PREPARATION, CHARACTERIZATION AND THERMAL DECOMPOSITION OF PRASEODYMIUM, TERBIUM AND NEODYMIUM CARBONATES Journal of Inorganic and Nuclear Chemistry. ,vol. 28, pp. 1165- 1177 ,(1966) , 10.1016/0022-1902(66)80442-6
Junnosuke Fujita, Arthur E. Martell, Kazuo Nakamoto, Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes The Journal of Chemical Physics. ,vol. 36, pp. 339- 345 ,(1962) , 10.1063/1.1732506
I. M. Kolthoff, Ruth. Elmquist, THE QUANTITATIVE DETERMINATION OF LANTHANUM BY PRECIPITATION AS OXALATE OR AS HYDROXIDE AND THE HIGHER OXIDE FORMATION OF LANTHANUM Journal of the American Chemical Society. ,vol. 53, pp. 1225- 1232 ,(1931) , 10.1021/JA01355A005