Photoinduced reactions of organic compounds with transition metal complexes: IV. Thermal and photochemical reactions of PtCl62−- and PtCl42− with olefins and alcohols: Convenient synthesis of π-olefin complexes of platinum(II)☆
作者： G.B. Shul'pin , G.V. Nizova , P. Lederer
DOI: 10.1016/0022-328X(84)85063-9
关键词: Alcohol 、 Acetic acid 、 Acetone 、 Aliphatic compound 、 Photochemistry 、 Chemistry 、 Olefin fiber 、 Platinum 、 Transition metal 、 Alkyl
摘要: Abstract Olefinplatinum(II) π-complexes can be synthesized by the following methods: (i) heating a solution of an olefin, alcohol or alkyl acetate and PtCl62− in acetic acid; (ii) light irradiation olefin acetone; (iii) PtCl42− aqueous acetone. The possible mechanisms thermal photoinduced reactions are discussed.
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