Diaqua­tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ2O:O′)dicopper(II)(Cu—Cu)

作者: Guang-Bo Che , Chun-Bo Liu , Yun-Cheng Cui , Chuan-Bi Li

DOI: 10.1107/S1600536805034793

关键词: Hydrogen bondBasal planeTetraChemistryQuinolineCrystallographySupramolecular chemistry

摘要: The title complex, [Cu2(C16H10NO2)4(H2O)2], has a centrosymmetric wheel-shaped dinuclear structure in which two symmetry-related CuII centers are bridged by four carboxyl­ate groups of distinct 2-phenylquinoline-4-carboxyl­ate (phqc) ligands, the Cu—Cu separation being 2.6507 (12) A. Each center is five-coordinated O atoms basal plane and one atom water mol­ecule apical position. In addition, mol­ecules linked inter­molecular O—H⋯N hydrogen bonds to form one-dimensional supramolecular chain.

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