作者: Guang-Bo Che , Chun-Bo Liu , Yun-Cheng Cui , Chuan-Bi Li
DOI: 10.1107/S1600536805034793
关键词: Hydrogen bond 、 Basal plane 、 Tetra 、 Chemistry 、 Quinoline 、 Crystallography 、 Supramolecular chemistry
摘要: The title complex, [Cu2(C16H10NO2)4(H2O)2], has a centrosymmetric wheel-shaped dinuclear structure in which two symmetry-related CuII centers are bridged by four carboxylate groups of distinct 2-phenylquinoline-4-carboxylate (phqc) ligands, the Cu—Cu separation being 2.6507 (12) A. Each center is five-coordinated O atoms basal plane and one atom water molecule apical position. In addition, molecules linked intermolecular O—H⋯N hydrogen bonds to form one-dimensional supramolecular chain.