New one-dimensional mercury(II) coordination polymers built up from dispiro-dipyridyloxy-cyclotriphosphazene: Structural, thermal and UV–Vis absorption properties
作者： Derya Davarcı , Süreyya Oğuz Tümay , Elif Şenkuytu , Michael Wörle , Yunus Zorlu
DOI: 10.1016/J.POLY.2019.01.010
关键词: Chemistry 、 Thermogravimetric analysis 、 Crystallography 、 Coordination geometry 、 Orthorhombic crystal system 、 Titration 、 Thermal stability 、 Single crystal 、 Monoclinic crystal system 、 Crystal structure
摘要: Abstract Reactions of flexible polydendate ligand system dispiro-dipyridyloxy-cyclotriphosphazene (L) with a variety mercury(II) salts (HgX2) (X = I−, Cl−) afforded two one-dimensional coordination polymers, namely formulated as {[Hg(L)(I)2]}n (1) and {[Hg(L)(Cl)2]}n.(ACN)0,341 (2). The isolated crystalline compounds were structurally characterized by single crystal X-ray crystallography. structure analysis revealed that 1 2 crystallizes in the orthorhombic (space group Pccn) monoclinic P21/c), which L exhibited κ2N binding mode divalent Hg ions to form chain structures. central Hg2+ ion has distorted tetrahedral geometry. UV–Vis properties thermal stability complexes (1, 2) also investigated. experiments (titration continuous variation (Job’s plot) analysis) showed all spectrophotometric solution state supports complexes. According TGA analysis, polymers up 300 °C, but more than 2.
sci-hub.se 参考文章(54)
Design and construction of coordination polymers Wiley. ,(2009) , 10.1002/9780470467336
David Roger Turner, Suzanne M Neville, Stuart Robert Batten, Coordination Polymers: Design, Analysis and Application ,(2009)
Attila B�rces, Geometry optimization of metal complexes using natural internal coordinates: Representation of skeletal degrees of freedom Journal of Computational Chemistry. ,vol. 18, pp. 45- 55 ,(1997) , 10.1002/(SICI)1096-987X(19970115)18:1<45::AID-JCC5>3.0.CO;2-#
Vadapalli Chandrasekhar, Balasubramanian Murugesa Pandian, Ramachandran Azhakar, Synthesis, structure and metallation of spiro-N3P3(O2C12H8)(OC5H4N-2)4: A heptacoordinate Co(II) in the molecular structure of N3P3(O2C12H8)(OC5H4N-2)4·Co(NO3)2 Polyhedron. ,vol. 27, pp. 255- 262 ,(2008) , 10.1016/J.POLY.2007.09.026
Bo-Ra Kim, Ho-Tae Kim, DFT Study of the [Cu-Angiotensin II] 2+ Complex Structure Bulletin of The Korean Chemical Society. ,vol. 33, pp. 2407- 2410 ,(2012) , 10.5012/BKCS.2012.33.7.2407
Eric W. Ainscough, Andrew M. Brodie, Craig V. Depree, Geoffrey B. Jameson, Carl A. Otter, Polymer building blocks: self-assembly of silver(I) cyclotriphosphazene cationic columns. Inorganic Chemistry. ,vol. 44, pp. 7325- 7327 ,(2005) , 10.1021/IC051334Y
Vadapalli Chandrasekhar, Ramakirushnan Suriya Narayanan, Metalation studies of 3- and 4-pyridyloxycyclophosphazenes: metallamacrocycles to coordination polymers Dalton Transactions. ,vol. 42, pp. 6619- 6632 ,(2013) , 10.1039/C3DT33084B
Eric W. Ainscough, Andrew M. Brodie, Ross J. Davidson, Carl A. Otter, The first coordination polymer containing a chiral cyclotriphosphazene ligand Inorganic Chemistry Communications. ,vol. 11, pp. 171- 174 ,(2008) , 10.1016/J.INOCHE.2007.12.001
Boris-Marko Kukovec, Ivan Kodrin, Vlasta Vojković, Zora Popović, Synthesis, X-ray structural, IR spectroscopic, thermal and DFT studies of nickel(II) and copper(II) complexes with 3-methylpicolinic acid. UV–Vis spectrophotometric study of complexation in the solution Polyhedron. ,vol. 52, pp. 1349- 1361 ,(2013) , 10.1016/J.POLY.2012.06.006
Vadapalli Chandrasekhar, Balasubramanian Murugesa Pandian, Ramachandran Azhakar, Di- and Trinuclear Complexes Derived from Hexakis(2-pyridyloxy)cyclotriphosphazene. Unusual P−O Bond Cleavage in the Formation of [{(L‘CuCl)2(Co(NO3)}Cl] (L‘ = N3P3(OC5H4N)5(O)) Inorganic Chemistry. ,vol. 45, pp. 3510- 3518 ,(2006) , 10.1021/IC0517467