Densities, speeds of sound, isentropic compressibilities, and refractive indices of binary mixtures of methyl methacrylate with hydrocarbons, haloalkanes and alkyl amines

作者: S.L. Oswal , B.M. Patel , A.M. Patel , N.Y. Ghael

DOI: 10.1016/S0378-3812(03)00031-1

关键词: ChemistryMethyl methacrylateCyclohexaneIsentropic processOrganic chemistryBenzeneChlorobenzeneButylamineToluenePropylamineAnalytical chemistry

摘要: Abstract Isentropic compressibilities K S , and thermal expansion coefficients α for methyl methacrylate, 1,2-dichloroethane (DCE), 1,1,2,2-tetrachloroethane (TCE), 1-chlorohexane, 1-bromohexane in the temperature range 298.15–333.15 K isentropic excess E molar volumes V 14 binary mixtures of methacrylate (MMA) with hexane, cyclohexane, benzene, toluene, chlorobenzene, tetrachloromethane, trichloromethane, 1,2-dichloroethane, 1,1,2,2-tetrachloroethane, 1-bromohexane, n -propylamine, -butylamine, tri- -butylamine over entire composition at 303.15 K, derived from experimental densities ρ speeds sound u have been reported. The values indicate varying extent molecular interactions interstitial accommodation between unlike components. analyzed terms collision factor theory (CFT) free length (FLT).

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