Highly efficient organic tandem solar cell based on SubPc:C-70 bulk heterojunction

作者: Fangming Jin , Bei Chu , Wenlian Li , Zisheng Su , Xingwu Yan

DOI: 10.1016/J.ORGEL.2014.10.019

关键词: Extraction (chemistry)Tandem solar cellAnalytical chemistryLayer (electronics)Energy conversion efficiencyStackingRecombinationPolymer solar cellMaterials scienceBoron

摘要: Highly efficient organic tandem solar cell with peak power conversion efficiency (PCE) of 7.66% has been demonstrated by simply stacking two same boron subphthalocyanine (SubPc):C-70 bulk heterojunction devices, a high active inter-connecting layer composed bathophenanthroline (Bphen)/Silver/hexadecafluoro-copper-phthalocyanine (F16CuPc)/MoO3. We find that F16CuPc plays an important role which extends the recombination zone, facilitates extraction hole and carrier recombination. The measured PCE corresponds to 38% increase compared optimal single cell. (C) 2014 Elsevier B.V. All rights reserved.

参考文章(23)
Minlu Zhang, Hui Wang, C.W. Tang, Tandem photovoltaic cells based on low-concentration donor doped C60 Organic Electronics. ,vol. 13, pp. 249- 251 ,(2012) , 10.1016/J.ORGEL.2011.11.004
D. W. Zhao, X. W. Sun, C. Y. Jiang, A. K. K. Kyaw, G. Q. Lo, D. L. Kwong, Efficient tandem organic solar cells with an Al/MoO3 intermediate layer Applied Physics Letters. ,vol. 93, pp. 083305- ,(2008) , 10.1063/1.2976126
Kenji Kawano, Norihiro Ito, Taisuke Nishimori, Jun Sakai, Open circuit voltage of stacked bulk heterojunction organic solar cells Applied Physics Letters. ,vol. 88, pp. 073514- ,(2006) , 10.1063/1.2177633
Minlu Zhang, Hui Wang, Hongkun Tian, Yanhou Geng, Ching. W. Tang, Bulk Heterojunction Photovoltaic Cells with Low Donor Concentration Advanced Materials. ,vol. 23, pp. 4960- 4964 ,(2011) , 10.1002/ADMA.201102173
Ya-Dong Liu, Bei Chu, Zi-Sheng Su, Wen-Lian Li, Tao-Jun Zhuang, Fang-Ming Jin, Xing-Wu Yan, Bo Zhao, Feng Zhang, Di Fan, Jun-Bo Wang, Yuan Gao, Mechanisms of the improved organic photovoltaic performance by using electron-transporting CuPc derivative as anode modifying layer Organic Electronics. ,vol. 13, pp. 2865- 2869 ,(2012) , 10.1016/J.ORGEL.2012.08.027
Guo Chen, Hisahiro Sasabe, Zhongqiang Wang, Xiao-Feng Wang, Ziruo Hong, Yang Yang, Junji Kido, Co-Evaporated Bulk Heterojunction Solar Cells with >6.0% Efficiency Advanced Materials. ,vol. 24, pp. 2768- 2773 ,(2012) , 10.1002/ADMA.201200234
Fangming Jin, Bei Chu, Wenlian Li, Zisheng Su, Bo Zhao, Tianyou Zhang, Xingwu Yan, Yuan Gao, Hairuo Wu, C.S. Lee, Jianzhuo Zhu, Huachun Pi, Junbo Wang, The influence of donor material on achieving high photovoltaic response for organic bulk heterojunction cells with small ratio donor component Organic Electronics. ,vol. 14, pp. 1130- 1135 ,(2013) , 10.1016/J.ORGEL.2013.01.026
Jianbing Yang, Weichao Chen, Bo Yu, Haibo Wang, Donghang Yan, Organic tandem solar cell using active inter-connecting layer Organic Electronics. ,vol. 13, pp. 1018- 1022 ,(2012) , 10.1016/J.ORGEL.2012.02.015
Xingwu Yan, Bei Chu, Wenlian Li, Zisheng Su, Tianyou Zhang, Fangming Jin, Bo Zhao, Feng Zhang, Di Fan, Yuan Gao, Taiju Tsuboi, Junbo Wang, Huajun Pi, Jianzhuo Zhu, Improved photovoltaic characteristics of organic cells with heterointerface layer as a hole-extraction layer inserted between ITO anode and donor layer Organic Electronics. ,vol. 14, pp. 1805- 1810 ,(2013) , 10.1016/J.ORGEL.2013.04.009
Yan-qiong Zheng, William J. Potscavage, Takeshi Komino, Masaya Hirade, Junji Adachi, Chihaya Adachi, Highly efficient bulk heterojunction photovoltaic cells based on C70 and tetraphenyldibenzoperiflanthene Applied Physics Letters. ,vol. 102, pp. 143304- ,(2013) , 10.1063/1.4801647