New high-pressure structural transition of oxygen at 96 GPa associated with metallization in a molecular solid.
作者： Yuichi Akahama , Haruki Kawamura , Daniel Häusermann , Michael Hanfland , Osamu Shimomura
DOI: 10.1103/PHYSREVLETT.74.4690
关键词: Isostructural 、 Molecular solid 、 Monoclinic crystal system 、 Materials science 、 Oxygen 、 Synchrotron radiation 、 Analytical chemistry 、 Lattice constant 、 Synchrotron Radiation Source 、 Solid oxygen
摘要: By using a high-energy and high-brilliance synchrotron radiation source in the European Synchrotron Radiation Facility Photon Factory, an angle-dispersive powder x-ray diffraction study of solid oxygen has been carried out up to 116 GPa at room temperature. A new high-pressure structural transition was observed 96 explained as isostructural with discontinuous change lattice constants monoclinic cell. Metallization reported by Desgreniers, Vohra, Ruoff [J. Phys. Chem. 94, 1117 (1990)] is ascribed transition.
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sci-hub.se 参考文章(21)
Russel J Hemley, HK Mao, Optical Studies of Hydrogen Above 200 Gigapascals: Evidence for Metallization by Band Overlap Science. ,vol. 244, pp. 1462- 1465 ,(1989) , 10.1126/SCIENCE.244.4911.1462
Jon H. Eggert, Fred Moshary, William J. Evans, Hector E. Lorenzana, Kenneth A. Goettel, Isaac F. Silvera, William C. Moss, Absorption and reflectance in hydrogen up to 230 GPa: Implications for metallization. Physical Review Letters. ,vol. 66, pp. 193- 196 ,(1991) , 10.1103/PHYSREVLETT.66.193
M. Hanfland, R. J. Hemley, H. K. Mao, Optical absorption measurements of hydrogen at megabar pressures. Physical Review B. ,vol. 43, pp. 8767- 8770 ,(1991) , 10.1103/PHYSREVB.43.8767
Arthur L. Ruoff, Craig A. Vanderborgh, Hydrogen reduction of ruby at high pressure: Implication for claims of metallic hydrogen. Physical Review Letters. ,vol. 66, pp. 754- 757 ,(1991) , 10.1103/PHYSREVLETT.66.754
Serge. Desgreniers, Yogesh K. Vohra, Arthur L. Ruoff, Optical response of very high density solid oxygen to 132 GPa The Journal of Physical Chemistry. ,vol. 94, pp. 1117- 1122 ,(1990) , 10.1021/J100366A020
Malcolm Nicol, K.R. Hirsch, Wilfried B. Holzapfel, Oxygen phase equilibria near 298 K Chemical Physics Letters. ,vol. 68, pp. 49- 52 ,(1979) , 10.1016/0009-2614(79)80066-4
H. D'Amour, W. B. Holzapfel, M. Nicol, Solid oxygen near 298 K. The structure of .beta.-oxygen and identification of a new .epsilon. phase The Journal of Physical Chemistry. ,vol. 85, pp. 130- 131 ,(1981) , 10.1021/J150602A003
D. Schiferl, D. T. Cromer, L. A. Schwalbe, R. L. Mills, Structure of 'orange' 18O2 at 9.6 GPa and 297 K Acta Crystallographica Section B-structural Science. ,vol. 39, pp. 153- 157 ,(1983) , 10.1107/S0108768183002219
D. Schiferl, S. W. Johnson, A. S. Zinn, High-temperature/high-pressure X-ray diffraction: Recent developments High Pressure Research. ,vol. 4, pp. 293- 295 ,(1990) , 10.1080/08957959008246100
S. W. Johnson, M. Nicol, D. Schiferl, Algorithm for sorting diffraction data from a sample consisting of several crystals enclosed in a sample environment apparatus Journal of Applied Crystallography. ,vol. 26, pp. 320- 326 ,(1993) , 10.1107/S0021889892008422