Diffusion parameters estimation of holographic memories based in PVA/acrylamide photopolymer

作者: Sergi Gallego , M. Ortuno , Cristian Neipp , A. Marquez , A. Belendez

DOI: 10.1117/12.605081

关键词: Fick's laws of diffusionDiffusion (business)PolymerMaterials scienceComposite materialMonomerHolographyOpticsWork (thermodynamics)PolymerizationPhotopolymer

摘要: The hard research about the models to predict and understand behaviour of photopolymers have as a results many interesting works for 2-dimensional cases. These studies permits obtain mains parameters that governs process in with maximum thickness 200 μm. Historically this materials, dry layers photopolymers, been used attractive devices now new application type material is being developed: holographic memories. main characteristics these are their high (higher than 600 μm). In order optimize original photopolymer composition has changed, then estimation be done. work study made using PVA/Acrylamide around 800 μm thick. values monomer polymer diffusion obtained polymerization rate constant residual calculated too first harmonic constant. validity model evaluated, because materials only few percent initial light arrive depth zones photopolymer.

参考文章(27)
Paul J. Flory, Principles of polymer chemistry ,(1953)
Sergi Gallego, Cristian Neipp, Manuel Ortuno, Andres Marquez, Augusto Belendez, Inmaculada Pascual, None, Diffusion-based model to predict the conservation of gratings recorded in poly(vinyl alcohol)–acrylamide photopolymer Applied Optics. ,vol. 42, pp. 5839- 5845 ,(2003) , 10.1364/AO.42.005839
Allen Pu, Kevin R Curtis, Demetri Psaltis, Exposure schedule for multiplexing holograms in photopolymer films Optical Engineering. ,vol. 35, pp. 2824- 2829 ,(1996) , 10.1117/1.600967
Sergi Gallego, Cristian Neipp, Manuel Ortuñto, Augusto Belendez, Inmaculada Pascual, None, Stabilization of volume gratings recorded in polyvinyl alcohol-acrylamide photopolymers with diffraction efficiencies higher than 90% Journal of Modern Optics. ,vol. 51, pp. 491- 503 ,(2004) , 10.1080/09500340408238063
Pavel Cheben, Marı́a L. Calvo, A photopolymerizable glass with diffraction efficiency near 100% for holographic storage Applied Physics Letters. ,vol. 78, pp. 1490- 1492 ,(2001) , 10.1063/1.1354665
C. Neipp, A. Beléndez, S. Gallego, M. Ortuño, I. Pascual, J. Sheridan, Angular responses of the first and second diffracted orders in transmission diffraction grating recorded on photopolymer material Optics Express. ,vol. 11, pp. 1835- 1843 ,(2003) , 10.1364/OE.11.001835
M. G. Moharam, T. K. Gaylord, Eric B. Grann, Drew A. Pommet, Formulation for stable and efficient implementation of the rigorous coupled-wave analysis of binary gratings Journal of the Optical Society of America A. ,vol. 12, pp. 1068- 1076 ,(1995) , 10.1364/JOSAA.12.001068
S. Martin, C. A. Feely, V. Toal, Holographic recording characteristics of an acrylamide-based photopolymer. Applied Optics. ,vol. 36, pp. 5757- 5768 ,(1997) , 10.1364/AO.36.005757
D. Psaltis, G.W. Burr, Holographic data storage IEEE Computer. ,vol. 31, pp. 52- 60 ,(1998) , 10.1109/2.652917
Sergi Gallego Rico, Manuel Ortuño Sánchez, Cristian Neipp López, Celia García Llopis, Augusto Beléndez Vázquez, Inmaculada Pascual Villalobos, Temporal evolution of the angular response of a holographic diffraction grating in PVA/acrylamide photopolymer Optics Express. ,vol. 11, pp. 181- 190 ,(2003) , 10.1364/OE.11.000181