Alcohol oxidation on nanocrystalline oxide Pd/C promoted electrocatalysts
作者： Pei Kang Shen , Changwei Xu
DOI: 10.1016/J.ELECOM.2005.11.013
关键词: Ethylene glycol 、 Ethanol 、 Alcohol oxidation 、 Electrocatalyst 、 Catalysis 、 Non-blocking I/O 、 Inorganic chemistry 、 Oxide 、 Chemistry 、 Methanol
摘要: Pd/C promoted with nanocrystalline oxides electrocatalysts were prepared by the intermittent microwave heating. The electrooxidation of methanol, ethanol, glycerol and ethylene glycol on CeO2 ,C o 3O4, Mn3O4 NiO catalysts in alkaline media was studied. Such are superior to Pt-based terms activity poison tolerance. most significant result is that onset potential for ethanol oxidation Pd–NiO/C electrocatalyst shifted negatively 300 mV compared Pt/C under same experimental conditions. electrochemical parameters measured analyzed. � 2005 Elsevier B.V. All rights reserved.
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