Magnetic nanocatalysts utilized in the synthesis of aromatic pharmaceutical ingredients

作者: Ali Maleki , Reza Taheri-Ledari

DOI: 10.1039/D0NJ06022D

关键词: Nanomaterial-based catalystGreen chemistryPyrroleActive ingredientSurface modificationChemistryOrganic reactionNanotechnologyAzideRaw material

摘要: Here, we provide a brief survey of the recent advances in catalytic processes used organic reactions, focusing on magnetic heterogeneous nanocatalysts (MHNCs). In last decade, many have been designed and applied to complex reaction procedures for syntheses active pharmaceutical ingredients (APIs). One most reported applications is facilitation multicomponent reactions (MCRs) by utilizing various composite structures. The high biodegradability biocompatibility MHNCs that comply with green chemistry principles greatly favor use these types material. Moreover, instead time-consuming purification because they can be separated highly convenient process. There are also other advantages such as preparation routes (including low-cost raw materials), surface functionalization capability, structural stability. this survey, try summarize progress field applicable synthesis APIs biphenyl, pyrrole, benzyl azide derivatives, etc.

参考文章(81)
Patrice Fontaine, Géraldine Masson, Jieping Zhu, Synthesis of pyrroles by consecutive multicomponent reaction/[4 + 1] cycloaddition of alpha-iminonitriles with isocyanides. Organic Letters. ,vol. 11, pp. 1555- 1558 ,(2009) , 10.1021/OL9001619
Sandro Olveira, Simon P. Forster, Stefan Seeger, Nanocatalysis: Academic Discipline and Industrial Realities Journal of Nanotechnology. ,vol. 2014, pp. 324089- ,(2014) , 10.1155/2014/324089
Shouhu Xuan, Mingwei Chen, Lingyun Hao, Wanquan Jiang, Xinglong Gong, Yuan Hu, Zuyao Chen, None, Preparation and characterization of microsized FeCO3, Fe3O4 and Fe2O3 with ellipsoidal morphology Journal of Magnetism and Magnetic Materials. ,vol. 320, pp. 164- 170 ,(2008) , 10.1016/J.JMMM.2007.05.019
Jie Lu, Sohrab Rohani, Polymorphism and crystallization of active pharmaceutical ingredients (APIs). Current Medicinal Chemistry. ,vol. 16, pp. 884- 905 ,(2009) , 10.2174/092986709787549299
Avvari N. Prasad, Boningari Thirupathi, Gangadhara Raju, Rapelli Srinivas, Benjaram M. Reddy, One pot ‘click’ reaction: CuII–hydrotalcite catalyzed tandem synthesis of β-hydroxy triazoles via regioselective opening of epoxide followed by [3+2] cycloaddition Catalysis Science & Technology. ,vol. 2, pp. 1264- 1268 ,(2012) , 10.1039/C2CY20052J
R. B. Nasir Baig, Mallikarjuna N. Nadagouda, Rajender S. Varma, Carbon-coated magnetic palladium: applications in partial oxidation of alcohols and coupling reactions Green Chemistry. ,vol. 16, pp. 4333- 4338 ,(2014) , 10.1039/C4GC00748D
Atul Kumar, Ram Awatar Maurya, Siddharth Sharma, Mukesh Kumar, Gitika Bhatia, Synthesis and biological evaluation of N-aryl-1,4-dihydropyridines as novel antidyslipidemic and antioxidant agents. European Journal of Medicinal Chemistry. ,vol. 45, pp. 501- 509 ,(2010) , 10.1016/J.EJMECH.2009.10.036
Vivek Polshettiwar, Rajender S. Varma, Green chemistry by nano-catalysis Green Chemistry. ,vol. 12, pp. 743- 754 ,(2010) , 10.1039/B921171C
María Eugenia Letelier, Paz Entrala, Camilo López-Alarcón, Víctor González-Lira, Alfredo Molina-Berríos, Juan Cortés-Troncoso, José Jara-Sandoval, Paola Santander, Luis Núñez-Vergara, Nitroaryl-1,4-dihydropyridines as antioxidants against rat liver microsomes oxidation induced by iron/ascorbate, nitrofurantoin and naphthalene. Toxicology in Vitro. ,vol. 21, pp. 1610- 1618 ,(2007) , 10.1016/J.TIV.2007.06.001