New preparation method of 3,4-disubstituted polypyrrole films by chemical oxidation

作者: T. Kaneko , H. Suzuki , N. Matsui , T. Shimidzu

DOI: 10.1016/0379-6779(91)91090-W

关键词: PolymerizationPyrrolePreparation methodInfrared spectroscopyChemical structurePolymer chemistryPolypyrroleMaterials scienceElectrochemistry

摘要: Abstract 3,4-disubstituted polypyrrole films were prepared by chemical oxidation and their structure some properties investigated. The polymerization was carried out evaporating solvents of the solution contained pyrrole oxidized agent, e.g., FeCl3. Cyclic voltmmograms IR spectra data indicated that electrochemical behavior present are similar to electropolymerized ones. These have good mechanical conductivities.

参考文章(8)
Tokushige Shichiri, Michio Toriumi, Kazuyoshi Tanaka, Tokio Yamabe, Jun Yamauchi, Yasuo Deguchi, ESR study for the oxidation of pyrrole in the presence of a spin trap Synthetic Metals. ,vol. 33, pp. 389- 397 ,(1989) , 10.1016/0379-6779(89)90484-0
Hideyuku Masuda, Susumu Tanaka, Kyoji Kaeriyama, Preparation of poly(3-octylpyrrole) by oxidative coupling Synthetic Metals. ,vol. 33, pp. 365- 372 ,(1989) , 10.1016/0379-6779(89)90481-5
So-ichi Yabuki, Hiroaki Shinohara, Masuo Aizawa, Electro-conductive enzyme membrane Journal of The Chemical Society, Chemical Communications. pp. 945- 946 ,(1989) , 10.1039/C39890000945
Steven P. Armes, Mahmoud Aldissi, Novel colloidal dispersons of polyaniline Journal of The Chemical Society, Chemical Communications. pp. 88- 89 ,(1989) , 10.1039/C39890000088
Masaharu Satoh, Keiichi Kaneto, Katsumi Yoshino, Highly Conducting Polypyrrole Prepared by Electrochemical Oxidation Method in Aqueous Solution Japanese Journal of Applied Physics. ,vol. 24, pp. L423- L424 ,(1985) , 10.1143/JJAP.24.L423
T. Hagiwara, M. Yamaura, K. Sato, M. Hirasaka, K. Iwata, Synthesis and properties of poly(3,4-dimethoxythiophene) Synthetic Metals. ,vol. 32, pp. 367- 379 ,(1989) , 10.1016/0379-6779(89)90778-9
Katsumi Yoshino, Shigenori Hayashi, Ryu-ichi Sugimoto, Preparation and Properties of Conducting Heterocyclic Polymer Films by Chemical Method Japanese Journal of Applied Physics. ,vol. 23, pp. L899- L900 ,(1984) , 10.1143/JJAP.23.L899
Masao Abe, Akira Ohtani, Yasuhiro Umemoto, Shinya Akizuki, Minoru Ezoe, Hiroyuki Higuchi, Keiji Nakamoto, Akitoshi Okuno, Yuzuru Noda, Soluble and high molecular weight polyaniline Journal of The Chemical Society, Chemical Communications. pp. 1736- 1738 ,(1989) , 10.1039/C39890001736