Stable and catalytically active iron porphyrin-based porous organic polymer: Activity as both a redox and Lewis acid catalyst
作者： Ali R. Oveisi , Kainan Zhang , Ahmad Khorramabadi-zad , Omar K. Farha , Joseph T. Hupp
DOI: 10.1038/SREP10621
关键词: Chemistry 、 Regioselectivity 、 BET theory 、 Benzyl alcohol 、 Lewis acid catalysis 、 Catalysis 、 Aminal 、 Styrene oxide 、 Porphyrin 、 Polymer chemistry
摘要: A new porphyrin-based porous organic polymer (POP) with BET surface area ranging from 780 to 880 m(2)/g was synthesized in free-base form via the reaction of meso-tetrakis(pentafluorophenyl) porphyrin and a rigid trigonal building block, hexahydroxytriphenylene. The material then metallated Fe(III) imparting activity for Lewis acid catalysis (regioselective methanolysis ring-opening styrene oxide), oxidative cyclization (conversion bis(2-hydroxy-1-naphthyl)methanes corresponding spirodienone), tandem catalytic processes: an situ oxidation-cyclic aminal formation-oxidation sequence, which selectively converts benzyl alcohol 2-phenyl-quinazolin-4(3H)-one. Notably, catalyst is readily recoverable reusable, little loss activity.
nature.com
harvard.edu
elsevier.com
sci-hub.se 参考文章(57)
G. K. Surya Prakash, George A. Olah, Synthetic methods and reactions Proceedings of the Indian Academy of Sciences - Chemical Sciences. ,vol. 100, pp. 143- 185 ,(1988) , 10.1007/BF02839446
Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis fmfg. ,vol. 293, ,(2010) , 10.1007/978-3-642-14613-8
Basudeb Saha, Dinesh Gupta, Mahdi M Abu-Omar, Arindam Modak, Asim Bhaumik, None, Porphyrin-based porous organic polymer-supported iron(III) catalyst for efficient aerobic oxidation of 5-hydroxymethyl-furfural into 2,5-furandicarboxylic acid Journal of Catalysis. ,vol. 299, pp. 316- 320 ,(2013) , 10.1016/J.JCAT.2012.12.024
Helen J. Mackintosh, Peter M. Budd, Neil B. McKeown, Catalysis by microporous phthalocyanine and porphyrin network polymers Journal of Materials Chemistry. ,vol. 18, pp. 573- 578 ,(2008) , 10.1039/B715660J
Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp, SonBinh T. Nguyen, A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts Journal of the American Chemical Society. ,vol. 131, pp. 4204- 4205 ,(2009) , 10.1021/JA900203F
Omar K. Farha, Alexander M. Spokoyny, Brad G. Hauser, Youn-Sang Bae, Samantha E. Brown, Randall Q. Snurr, Chad A. Mirkin, Joseph T. Hupp, Synthesis, Properties, and Gas Separation Studies of a Robust Diimide-Based Microporous Organic Polymer Chemistry of Materials. ,vol. 21, pp. 3033- 3035 ,(2009) , 10.1021/CM901280W
Wenlei Ge, Xun Zhu, Yunyang Wei, Iodine-catalyzed oxidative system for cyclization of primary alcohols with o-aminobenzamides to quinazolinones using DMSO as the oxidant in dimethyl carbonate RSC Advances. ,vol. 3, pp. 10817- 10822 ,(2013) , 10.1039/C3RA40872H
Yugen Zhang, Siti Nurhanna Riduan, Functional porous organic polymers for heterogeneous catalysis Chem. Soc. Rev.. ,vol. 41, pp. 2083- 2094 ,(2012) , 10.1039/C1CS15227K
Long Chen, Yong Yang, Donglin Jiang, CMPs as scaffolds for constructing porous catalytic frameworks: a built-in heterogeneous catalyst with high activity and selectivity based on nanoporous metalloporphyrin polymers. Journal of the American Chemical Society. ,vol. 132, pp. 9138- 9143 ,(2010) , 10.1021/JA1028556
Lihong Zhang, Chenhui Hu, Junfeng Zhang, Liyuan Cheng, Zheng Zhai, Jing Chen, Weiping Ding, Wenhua Hou, Sulfur and iron co-doped titanoniobate nanosheets: a novel efficient solid acid catalyst for alcoholysis of styrene epoxide at room temperature Chemical Communications. ,vol. 49, pp. 7507- 7509 ,(2013) , 10.1039/C3CC42951B