Size-Controllable and Low-Cost Fabrication of Graphene Quantum Dots Using Thermal Plasma Jet

作者: Juhan Kim , Jung Sang Suh

DOI: 10.1021/NN404180W

关键词: Quantum dotAnalytical chemistryAnodePlasmaFabricationMaterials scienceCarbonSootGraphenePhotoluminescenceGeneral EngineeringGeneral Physics and AstronomyGeneral Materials Science

摘要: We report a size-controllable and low-cost fabrication method of graphene quantum dots (GQDs) using thermal plasma jet. A carbon atomic beam was generated by injecting large amount (2.5 L/min) ethylene gas continuously into Ar plasma. The then flowed through tube (5–20 cm in length) attached to the anode dispersed chamber. Carbon materials including GQDs were made phase collision reaction. production rate soot 40 g/h for 2.5 L/min injection rate. Almost all ethanol sonication, while isolated stirring with rod. weight percent soot, based on extracted ethanol, about 10%. This means that 4 g/h. average size GQDs, relatively narrow distribution, controlled varying length attached. It 10, 14, 19 nm when 5, 10,...

参考文章(37)
W. A. de Heer, C. Berger, T. Li, J. Hass, R. Feng, C. A. Jeffrey, P. N. First, Z. Zong, E. H. Conrad, X. Li, Highly ordered graphene for two dimensional electronics Applied Physics Letters. ,vol. 89, pp. 143106- ,(2006) , 10.1063/1.2358299
Xin Yan, Xiao Cui, Liang-shi Li, Synthesis of large, stable colloidal graphene quantum dots with tunable size. Journal of the American Chemical Society. ,vol. 132, pp. 5944- 5945 ,(2010) , 10.1021/JA1009376
Dmitry V. Kosynkin, Amanda L. Higginbotham, Alexander Sinitskii, Jay R. Lomeda, Ayrat Dimiev, B. Katherine Price, James M. Tour, Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons Nature. ,vol. 458, pp. 872- 876 ,(2009) , 10.1038/NATURE07872
Ljubisa R. Radovic, Bradley Bockrath, On the chemical nature of graphene edges: origin of stability and potential for magnetism in carbon materials. Journal of the American Chemical Society. ,vol. 127, pp. 5917- 5927 ,(2005) , 10.1021/JA050124H
Joeoong Hahn, Soo Bong Heo, Jung Sang Suh, Catalyst free synthesis of high-purity carbon nanotubes by thermal plasma jet Carbon. ,vol. 43, pp. 2638- 2641 ,(2005) , 10.1016/J.CARBON.2005.05.013
Yan Li, Yue Hu, Yang Zhao, Gaoquan Shi, Lier Deng, Yanbing Hou, Liangti Qu, An Electrochemical Avenue to Green‐Luminescent Graphene Quantum Dots as Potential Electron‐Acceptors for Photovoltaics Advanced Materials. ,vol. 23, pp. 776- 780 ,(2011) , 10.1002/ADMA.201003819
Jinsup Lee, Kyungho Kim, Woon Ik Park, Bo-Hyun Kim, Jong Hyun Park, Tae-Heon Kim, Sungyool Bong, Chul-Hong Kim, GeeSung Chae, Myungchul Jun, Yongkee Hwang, Yeon Sik Jung, Seokwoo Jeon, Uniform graphene quantum dots patterned from self-assembled silica nanodots. Nano Letters. ,vol. 12, pp. 6078- 6083 ,(2012) , 10.1021/NL302520M
A. K. Geim, K. S. Novoselov, The rise of graphene Nature Materials. ,vol. 6, pp. 183- 191 ,(2007) , 10.1038/NMAT1849
Dengyu Pan, Jingchun Zhang, Zhen Li, Minghong Wu, None, Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots Advanced Materials. ,vol. 22, pp. 734- 738 ,(2010) , 10.1002/ADMA.200902825
Fei Liu, Min-Ho Jang, Hyun Dong Ha, Je-Hyung Kim, Yong-Hoon Cho, Tae Seok Seo, Facile Synthetic Method for Pristine Graphene Quantum Dots and Graphene Oxide Quantum Dots: Origin of Blue and Green Luminescence Advanced Materials. ,vol. 25, pp. 3657- 3662 ,(2013) , 10.1002/ADMA.201300233