One-pot synthesis of a composite of monodispersed CuO nanospheres on carbon nanotubes as anode material for lithium-ion batteries

作者: Syed Mustansar Abbas , Syed Tajammul Hussain , Saqib Ali , Faisal Abbas , Nisar Ahmad

DOI: 10.1016/J.JALLCOM.2013.04.197

关键词: Materials scienceTransmission electron microscopyScanning electron microscopeAnalytical chemistryDispersion (chemistry)Cyclic voltammetryCarbon nanotubeComposite numberLithiumFourier transform infrared spectroscopy

摘要: Abstract Nanospheres of CuO are synthesized by a facile solution reaction CuCl 2 in the presence carbon nanotubes (CNTs), yielding composite material. Transmission electron microscopy (TEM) confirms uniform dispersion nanospheres on CNTs surface. The functional groups determined Fourier transform infrared spectroscopy (FTIR) and elemental composition is confirmed Rutherford backscattering (RBS), while structure morphology deposited electrodes investigated X-ray diffraction (XRD) scanning (SEM), respectively. Electrochemical characterization cyclic voltammetry (CV) galvanostatic charge/discharge tests demonstrate high rate capability superior cycling stability for CuO/CNT with specific capacity 638 mAh/g up to 50 cycles. It anticipated that this efficiency due excellent conductivity mesh.

参考文章(32)
J.Y. Xiang, J.P. Tu, L. Zhang, Y. Zhou, X.L. Wang, S.J. Shi, Self-assembled synthesis of hierarchical nanostructured CuO with various morphologies and their application as anodes for lithium ion batteries Journal of Power Sources. ,vol. 195, pp. 313- 319 ,(2010) , 10.1016/J.JPOWSOUR.2009.07.022
Mengwei Wang, Hailei Zhao, Jianchao He, Ronglin Wang, Jingbo Chen, Ning Chen, Preparation and electrochemical performance of CoSb alloy anode material for Li-ion batteries Journal of Alloys and Compounds. ,vol. 484, pp. 864- 869 ,(2009) , 10.1016/J.JALLCOM.2009.05.063
J. Maier, Nanoionics: ion transport and electrochemical storage in confined systems. Nature Materials. ,vol. 4, pp. 805- 815 ,(2005) , 10.1038/NMAT1513
Fangwei Zhan, Hui Zhang, Yue Qi, Jiazheng Wang, Ning Du, Deren Yang, Electrochemical synthesis of SnCo alloy shells on orderly rod-shaped Cu current collectors as anode materials for lithium-ion batteries with enhanced performance Journal of Alloys and Compounds. ,vol. 570, pp. 119- 124 ,(2013) , 10.1016/J.JALLCOM.2013.02.154
Xiaoming Lou, Xiaozhen Wu, Youxiang Zhang, A study about γ-MnOOH nanowires as anode materials for rechargeable Li-ion batteries Journal of Alloys and Compounds. ,vol. 550, pp. 185- 189 ,(2013) , 10.1016/J.JALLCOM.2012.09.124
Charles de las Casas, Wenzhi Li, A review of application of carbon nanotubes for lithium ion battery anode material Journal of Power Sources. ,vol. 208, pp. 74- 85 ,(2012) , 10.1016/J.JPOWSOUR.2012.02.013
B. Wang, J.L. Cheng, Y.P. Wu, D. Wang, D.N. He, Porous NiO fibers prepared by electrospinning as high performance anode materials for lithium ion batteries Electrochemistry Communications. ,vol. 23, pp. 5- 8 ,(2012) , 10.1016/J.ELECOM.2012.07.003
Guodong Du, Chao Zhong, Peng Zhang, Zaiping Guo, Zhixin Chen, Huakun Liu, Tin dioxide/carbon nanotube composites with high uniform SnO2 loading as anode materials for lithium ion batteries Electrochimica Acta. ,vol. 55, pp. 2582- 2586 ,(2010) , 10.1016/J.ELECTACTA.2009.12.031
Zhibin Zhou, Yunhua Xu, Mirabbos Hojamberdiev, Wengang Liu, Juan Wang, Enhanced cycling performance of silicon/disordered carbon/carbon nanotubes composite for lithium ion batteries Journal of Alloys and Compounds. ,vol. 507, pp. 309- 311 ,(2010) , 10.1016/J.JALLCOM.2010.07.188