Role of nickel alloying on anodic dissolution behavior of zinc in 3.5% NaCl solution. Part II: Potentiodynamic, potentiostatic and galvanostatic studies

作者: Hany M. ABD EL-LATEEF , Abdel-Rahman EL-SAYED , Hossnia S. MOHRAN

DOI: 10.1016/S1003-6326(15)63946-2

关键词: AlloyMetal hydroxideZincInorganic chemistryMaterials scienceChlorideMetalMicrostructureCorrosionNickel

摘要: Abstract Zinc is common metal used for steel protection from corrosion. The addition of further element, such as Ni, can modify the corrosion rate and maintain sacrificial protection. anodic dissolution behavior Zn, Ni Zn–Ni alloys with different contents (from 0.5% to 10%, mass fraction) in 3.5% NaCl solution was investigated using potentiodynamic, potentiostatic galvanostatic techniques. composition microstructure layer on were characterized by energy-dispersive X-ray spectroscopy analysis (EDX) scanning electron microscopy (SEM). curves show that all electrodes exhibits active/passive transition tendency passivity decreases increase content, except 99.5Zn–0.5Ni alloy. While potentiodynamic exhibit active passive only pure Zn. Surface reveals presence oxides, chlorides hydroxide chloride products, very small cracks are observed 90Zn–10Ni alloy compared

参考文章(44)
Hany M. ABD EL-LATEEF, Abdel-Rahman EL-SAYED, Hossnia S. MOHRAN, Role of Ni content in improvement of corrosion resistance of Zn−Ni alloy in 3.5% NaCl solution. Part I: Polarization and impedance studies Transactions of Nonferrous Metals Society of China. ,vol. 25, pp. 2807- 2816 ,(2015) , 10.1016/S1003-6326(15)63906-1
F. J. Fabri Miranda, I. C. P. Margarit, O. R. Mattos, O. E. Barcia, R. Wiart, Corrosion Behavior of Zinc-Nickel Alloy Electrodeposited Coatings Corrosion. ,vol. 55, pp. 732- 742 ,(1999) , 10.5006/1.3284028
S. Mohan, V. Ravindran, B. Subramanian, G. Saravanan, Electrodeposition of zinc–nickel alloy by pulse plating using non-cyanide bath Transactions of The Institute of Metal Finishing. ,vol. 87, pp. 85- 89 ,(2009) , 10.1179/174591909X423600
E.E. Abd El Aal, Effect of Cl− anions on zinc passivity in borate solution Corrosion Science. ,vol. 42, pp. 1- 16 ,(2000) , 10.1016/S0010-938X(99)00052-9
I.S. Cole, W.D. Ganther, S.A. Furman, T.H. Muster, A.K. Neufeld, Pitting of zinc: Observations on atmospheric corrosion in tropical countries Corrosion Science. ,vol. 52, pp. 848- 858 ,(2010) , 10.1016/J.CORSCI.2009.11.002
Abdel-Rahman El-Sayed, Hossnia S. Mohran, Hany M. Abd El-Lateef, Corrosion Study of Zinc, Nickel, and Zinc-Nickel Alloys in Alkaline Solutions by Tafel Plot and Impedance Techniques Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science. ,vol. 43, pp. 619- 632 ,(2012) , 10.1007/S11661-011-0908-4
Digby D. Macdonald, Mirna Urquidi‐Macdonald, Theory of Steady‐State Passive Films Journal of The Electrochemical Society. ,vol. 137, pp. 2395- 2402 ,(1990) , 10.1149/1.2086949