Effect of pyridine and its derivatives on the electrodeposition of nickel from aqueous sulfate solutions. Part II : Polarization behaviour
作者： U.S. Mohanty , B.C. Tripathy , P. Singh , S.C. Das
关键词: Nickel 、 Polarization (electrochemistry) 、 Tafel equation 、 Pyridine 、 Chemistry 、 Sodium sulfate 、 Inorganic chemistry 、 Exchange current density 、 Electrochemistry 、 Linear sweep voltammetry
摘要: The electrochemical reactions occurring during electrodeposition of nickel from acidic sulfate solutions were examined by cyclic and linear sweep voltammetry techniques. effect pyridine, 2-picoline 4-picoline on the electrode polarization behaviour electron transfer parameter cathodic reduction process was also investigated. Strongest seen with 4-picoline. order > pyridine. Kinetic parameters such as Tafel slope, coefficient exchange current density determined to analyse nature reactions. for deposition stainless steel substrates in <
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