Surface functionalization of honeycomb-patterned porous poly(ε-caprolactone) films by interfacial polymerization of aniline
作者： Umashankar Male , Eun Jin Jo , Ju Yeon Park , Do Sung Huh
DOI: 10.1016/J.POLYMER.2016.07.040
关键词: Polymer 、 Polyaniline 、 Materials science 、 Caprolactone 、 Bulk polymerization 、 Polymerization 、 Aniline 、 Surface modification 、 Polymer chemistry 、 Interfacial polymerization
摘要: Abstract We present a new and facile strategy for the fabrication of conducting honeycomb-patterned porous films through interfacial polymerization. Polymer solutions containing poly(e-carprolactone) (PCL) benzoyl peroxide (BPO) in chloroform was fabricated under high humid conditions to obtain PCL-BPO honeycomb patterned films. The were treated with aqueous aniline hydrochloride solution polymerize at interface PCL film solution. served dual role template as well an oxidant. proposed retains electrical conductivity polyaniline mechanical strength biodegradable properties PCL. In contrast in-situ templated bulk polymerization methods, method exhibits advantage retaining porosity without causing any wreckage.
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