Mechanical and dielectric properties of microcellular polycarbonate foams with unimodal or bimodal cell-size distributions:

作者: Zhonglei Ma , Guangcheng Zhang , Quan Yang , Xuetao Shi , Yang Liu

DOI: 10.1177/0021955X14542989

关键词: Relative densityPolycarbonateCompressive strengthDynamic mechanical analysisDielectricDynamic modulusMaterials scienceComposite materialPorosityModulus

摘要: This article reports on the compressive, dynamic mechanical and dielectric properties of microcellular polycarbonate foams with unimodal or bimodal cell-size distributions fabricated using environment-friendly supercritical carbon dioxide. The effects cell morphologies such as relative density, distribution porosity compressive strength, Young’s modulus, storage loss constant tangent are investigated quantitatively. Experimental values strength modulus fit very well theoretical calculated from Gibson–Ashby model at low densities. higher density leads to modulus. significantly improve compared same density. depend only total porosity, bu...

参考文章(46)
Lorna J. Gibson, Michael F. Ashby, Cellular Solids: Structure and Properties ,(1988)
Jane Ellen Martini, The production and analysis of microcellular foam Massachusetts Institute of Technology. ,(1981)
Jin-Biao Bao, Tao Liu, Ling Zhao, Guo-Hua Hu, A two-step depressurization batch process for the formation of bi-modal cell structure polystyrene foams using scCO2 Journal of Supercritical Fluids. ,vol. 55, pp. 1104- 1114 ,(2011) , 10.1016/J.SUPFLU.2010.09.032
Jung-Hwan Seo, Sung Woon Cha, Hak Bin Kim, Diffused Reflection of Microcellular Foamed Polycarbonate Polymer-plastics Technology and Engineering. ,vol. 48, pp. 351- 358 ,(2009) , 10.1080/03602550902725332
Chul B. Park, Daniel F. Baldwin, Nam P. Suh, Effect of the pressure drop rate on cell nucleation in continuous processing of microcellular polymers Polymer Engineering and Science. ,vol. 35, pp. 432- 440 ,(1995) , 10.1002/PEN.760350509
H. J. Cha, J. Hedrick, R. A. DiPietro, T. Blume, R. Beyers, D. Y. Yoon, Structures and dielectric properties of thin polyimide films with nano‐foam morphology Applied Physics Letters. ,vol. 68, pp. 1930- 1932 ,(1996) , 10.1063/1.115629
Zhi-Mei Xu, Xiu-Lei Jiang, Tao Liu, Guo-Hua Hu, Ling Zhao, Zhong-Nan Zhu, Wei-Kang Yuan, Foaming of polypropylene with supercritical carbon dioxide Journal of Supercritical Fluids. ,vol. 41, pp. 299- 310 ,(2007) , 10.1016/J.SUPFLU.2006.09.007
Jae Hyun Kim, Jyongsik Jang, Wang-Cheol Zin, Thickness Dependence of the Glass Transition Temperature in Thin Polymer Films Langmuir. ,vol. 17, pp. 2703- 2710 ,(2001) , 10.1021/LA001125K
N.N. Najib, Z.M. Ariff, A.A. Bakar, C.S. Sipaut, Correlation between the acoustic and dynamic mechanical properties of natural rubber foam: Effect of foaming temperature Materials & Design. ,vol. 32, pp. 505- 511 ,(2011) , 10.1016/J.MATDES.2010.08.030