Ultra stable self-assembled monolayers of N-heterocyclic carbenes on gold

作者: Cathleen M. Crudden , J. Hugh Horton , Iraklii I. Ebralidze , Olena V. Zenkina , Alastair B. McLean

DOI: 10.1038/NCHEM.1891

关键词: Supramolecular chemistrySelf-assembled monolayerThiolChemistryMoleculeCarbeneInorganic chemistryMonolayerIonic bondingCovalent bondPhotochemistry

摘要: … bond is estimated to be on the order of 90 kJ mol −1 stronger than the corresponding Au–phosphine bond and double that of metal sulfide bonds … and functionalization of gold and other …

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