Isotropic and anisotropic collision-induced light scattering by gaseous sulfur hexafluoride at the frequency region of the ν1 vibrational Raman line
作者： Y. Le Duff , J.-L. Godet , T. Bancewicz , K. Nowicka
DOI: 10.1063/1.1575733
关键词: Ab initio quantum chemistry methods 、 Analytical chemistry 、 Rayleigh scattering 、 Molecular physics 、 Sulfur hexafluoride 、 Spectral line 、 Chemistry 、 Polarizability 、 Light scattering 、 Ab initio 、 Raman spectroscopy 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: Experimental binary isotropic and anisotropic Stokes spectra of the collision-induced light scattered by gaseous sulfur hexafluoride are measured at frequency region ν1 vibrational Raman line. They compared to theoretical intensities due dipole–multipole interactions. Taking into account results a previous study on interaction-induced in Rayleigh wings hexafluoride, an experimental value derivative dipole–octopole polarizability associated with mode is provided result recent ab initio calculation.
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