作者: Johannes A. Lercher , Frederik N. Naraschewski
DOI: 10.1039/9781847559876-00005
关键词: Redox 、 Halogenation 、 Oxide 、 Computational chemistry 、 Chemistry 、 Electrophilic substitution 、 Catalysis 、 Kinetic analysis 、 Organic chemistry
摘要: This chapter is focused on the initial activation step of C–H bonds in oxidation reactions. Model experiments, kinetic analysis complex reactions and theoretical studies will be combined to provide an overview current state insight into processes as well their potentials limitations. The covers oxide clusters, indirect via electrophilic substitution (chlorination bromination) influence anions nonreducible cations mechanism activation.