Chapter 2:C–H Activation of Alkanes in Selective Oxidation Reactions on Solid Oxide Catalysts

作者: Johannes A. Lercher , Frederik N. Naraschewski

DOI: 10.1039/9781847559876-00005

关键词: RedoxHalogenationOxideComputational chemistryChemistryElectrophilic substitutionCatalysisKinetic analysisOrganic chemistry

摘要: This chapter is focused on the initial activation step of C–H bonds in oxidation reactions. Model experiments, kinetic analysis complex reactions and theoretical studies will be combined to provide an overview current state insight into processes as well their potentials limitations. The covers oxide clusters, indirect via electrophilic substitution (chlorination bromination) influence anions nonreducible cations mechanism activation.

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