Preparation of N,F-codoped TiO2 nanoparticles by three different methods and comparison of visible-light photocatalytic performances

作者: Qing Guo , Zhaohong Zhang , Xiping Ma , Kui Jing , Manli Shen

DOI: 10.1016/J.SEPPUR.2016.11.041

关键词: NanoparticleMaterials scienceFluorineDispersion (chemistry)Hydrofluoric acidPhotocatalysisNanotechnologyDegradation (geology)Visible spectrumAnataseNuclear chemistry

摘要: Abstract In this work, three types of N,F-codoped TiO2 nanoparticles (N,F-TiO2) were synthesized using modified sol-gel methods, and applied in degradation acid red B (AR B), as a target pollutant solution. The extents the investigated to compare photocatalytic activities prepared photocatalysts. results show that anatase N,F-TiO2 can be obtained methods with significantly enhanced extents. rate under visible light alone is very slow, N,F-TiO2(1) by different adding sequence nitrogen fluorine sources, exhibits higher effect. Also, crystallite sizes dispersion particles, doped dose, treatment temperature have significant effects on activity. Moreover, more OH radicals are generated light, presence than those N,F-TiO2(2) double sol method, N,F-TiO2(3) direct method. Therefore, work suggests preparation hydrofluoric sources ammonia water promising, promising photocatalyst applications dealing dye wastewater solar light.

参考文章(39)
Helen Barndõk, Daphne Hermosilla, Changseok Han, Dionysios D. Dionysiou, Carlos Negro, Ángeles Blanco, Degradation of 1,4-dioxane from industrial wastewater by solar photocatalysis using immobilized NF-TiO2 composite with monodisperse TiO2 nanoparticles Applied Catalysis B-environmental. ,vol. 180, pp. 44- 52 ,(2016) , 10.1016/J.APCATB.2015.06.015
Anand Kulkarni, Changseok Han, Dhananjay Bhatkhande, Dionysios D. Dionysiou, Photocatalytic degradation of maleic anhydride using visible light-activated NF-codoped TiO2 Separation and Purification Technology. ,vol. 156, pp. 1011- 1018 ,(2015) , 10.1016/J.SEPPUR.2015.07.021
Yuwei Guo, Chunping Cheng, Jun Wang, Zhiqiu Wang, Xudong Jin, Kai Li, Pingli Kang, Jingqun Gao, None, Detection of reactive oxygen species (ROS) generated by TiO2(R), TiO2(R/A) and TiO2(A) under ultrasonic and solar light irradiation and application in degradation of organic dyes Journal of Hazardous Materials. ,vol. 192, pp. 786- 793 ,(2011) , 10.1016/J.JHAZMAT.2011.05.084
Miguel Pelaez, Polycarpos Falaras, Vlassis Likodimos, Athanassios G. Kontos, Armah A. de la Cruz, Kevin O'shea, Dionysios D. Dionysiou, Synthesis, structural characterization and evaluation of sol-gel-based NF-TiO2 films with visible light-photoactivation for the removal of microcystin-LR Applied Catalysis B-environmental. ,vol. 99, pp. 378- 387 ,(2010) , 10.1016/J.APCATB.2010.06.017
Jirapat Ananpattarachai, Puangrat Kajitvichyanukul, Supapan Seraphin, Visible light absorption ability and photocatalytic oxidation activity of various interstitial N-doped TiO2 prepared from different nitrogen dopants Journal of Hazardous Materials. ,vol. 168, pp. 253- 261 ,(2009) , 10.1016/J.JHAZMAT.2009.02.036
Jun Wang, Yuwei Guo, Bin Liu, Xudong Jin, Lijun Liu, Rui Xu, Yumei Kong, Baoxin Wang, None, Detection and analysis of reactive oxygen species (ROS) generated by nano-sized TiO2 powder under ultrasonic irradiation and application in sonocatalytic degradation of organic dyes Ultrasonics Sonochemistry. ,vol. 18, pp. 177- 183 ,(2011) , 10.1016/J.ULTSONCH.2010.05.002
Jun Wang, Yuwei Guo, Jingqun Gao, Xudong Jin, Zhiqiu Wang, Baoxin Wang, Kai Li, Ying Li, None, Detection and comparison of reactive oxygen species (ROS) generated by chlorophyllin metal (Fe, Mg and Cu) complexes under ultrasonic and visible-light irradiation. Ultrasonics Sonochemistry. ,vol. 18, pp. 1028- 1034 ,(2011) , 10.1016/J.ULTSONCH.2010.12.006
Junjing Li, Bo Li, Jiejing Li, Junliang Liu, Liang Wang, Hongwei Zhang, Zhaohui Zhang, Bin Zhao, Visible-light-driven photocatalyst of La–N-codoped TiO2 nano-photocatalyst: Fabrication and its enhanced photocatalytic performance and mechanism Journal of Industrial and Engineering Chemistry. ,vol. 25, pp. 16- 21 ,(2015) , 10.1016/J.JIEC.2014.09.042
Yongjun Chen, Dionysios D. Dionysiou, Bimodal mesoporous TiO2–P25 composite thick films with high photocatalytic activity and improved structural integrity Applied Catalysis B-environmental. ,vol. 80, pp. 147- 155 ,(2008) , 10.1016/J.APCATB.2007.11.010