Magnetic properties of linear chain compounds: copper(II) complexes with 2-(o-hydroxyphenyl)-benzoxazole and -benzothiazole
作者： John R. Wasson , H. Wayne Richardson , William E. Hatfield
DOI: 10.1016/0022-1902(77)80290-X
关键词: Benzothiazole 、 Chain (algebraic topology) 、 Chemistry 、 Medicinal chemistry 、 Copper 、 Atmospheric temperature range 、 Chain structure 、 Benzoxazole 、 Magnetic susceptibility 、 Photochemistry 、 Materials Chemistry 、 Polymers and Plastics
摘要: Abstract The magnetic susceptibility behavior of the copper(II) complexes 2-( o -hydroxyphenyl) benzoxazole and benzothiazole has been examined over temperature range 2–77°K. Despite established linear chain structure both exhibit negligible spin exchange coupling. present work provides additional support an earlier conclusion that out-of-plane copper-oxygen distances 2.8A or greater are too long to transmit spin-spin interactions.
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