Thermochemical properties of three isotypic polyborate cluster compounds: Na5[MB24O34(OH)12]·nH2O (M = Cr3+, Al3+, Ga3+)
作者： Qing Song , Qiu-Yue Kang , Sa-Ying Li , Qiu-Yan Yu , Zhi-Hong Liu
DOI: 10.1016/J.JCT.2013.12.027
关键词: Medicinal chemistry 、 Cluster (physics) 、 Thermodynamics 、 Enthalpy change of solution 、 Standard enthalpy of formation 、 Group contribution method 、 Thermochemical cycle 、 Chemistry 、 Enthalpy
摘要: Abstract Three isotypic polyborate cluster compounds for Na 5 [AlB 24 O 34 (OH) 12 ]·5.5H 2 O, [CrB ]·5H and [GaB ]·3H have been synthesized characterized by EDS, XRD, FT-IR, TG techniques chemical analysis. The molar enthalpies of solution (s) in 1 mol · dm −3 HCl (aq) were measured to be (58.27 ± 0.15) kJ · mol −1 (130.99 ± 0.33) kJ · mol , respectively. AlCl 3 ·6H CrCl (HCl + H BO + NaCl) also measured, With the incorporation previously determined enthalpy H (aq), together with standard formation (s)/CrCl (s), NaCl(s), (l), −(21316.0 ± 19.3) kJ · mol −(21669.7 ± 19.3) kJ · mol at T = 298.15 K obtained on basis appropriate thermochemical cycles. )]·3H was estimated as −20662.9 kJ · mol using a group contribution method these results.
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sci-hub.se 参考文章(15)
V. A. Medvedev, J. D. Cox, Donald D. Wagman, CODATA key values for thermodynamics Hemisphere Pub. Corp.. ,(1989)
Tao Yang, Junliang Sun, Lars Eriksson, Guobao Li, Xiaodong Zou, Fuhui Liao, Jianhua Lin, Na5[MB24O34(OH)12]·nH2O (M = Cr3+, Al3+): Unprecedented Spherelike Polyborate Clusters from Boric Acid Flux Synthesis Inorganic Chemistry. ,vol. 47, pp. 3228- 3233 ,(2008) , 10.1021/IC702244W
Chuangtian Chen, Yebin Wang, Baichang Wu, Keche Wu, Wenlun Zeng, Linhua Yu, None, Design and synthesis of an ultraviolet-transparent nonlinear optical crystal Sr 2 Be 2 B 2 O 7 Nature. ,vol. 373, pp. 322- 324 ,(1995) , 10.1038/373322A0
Mian Ji, Mingyan Liu, Shengli Gao, Qizhen Shi, A NEW MICROCALORIMETER FOR MEASURING THERMAL EFFECTS Instrumentation Science & Technology. ,vol. 29, pp. 53- 57 ,(2001) , 10.1081/CI-100001408
Donald D. Wagman, William H. Evans, Vivian B. Parker, Richard H. Schumm, Iva Halow, Sylvia M. Bailey, Kenneth L. Churney, Ralph L. Nuttall, Erratum: The NBS tables of chemical thermodynamic properties. Selected values for inorganic and C1 and C2 organic substances in SI units [J. Phys. Chem. Ref. Data 11, Suppl. 2 (1982)] Journal of Physical and Chemical Reference Data. ,vol. 18, pp. 1807- 1812 ,(1989) , 10.1063/1.555845
R Rychlý, V Pekárek, The use of potassium chloride and tris(hydroxymethyl)aminomethane as standard substances for solution calorimetry The Journal of Chemical Thermodynamics. ,vol. 9, pp. 391- 396 ,(1977) , 10.1016/0021-9614(77)90060-X
P. G. Hill, A Fundamental Equation of State for Heavy Water Journal of Physical and Chemical Reference Data. ,vol. 11, pp. 1- 14 ,(1982) , 10.1063/1.555661
Yang Lv, Ning Li, Mei Tang, Zhi-Hong Liu, Thermodynamic properties of microporous crystals for two hydrated aluminoborates, K2[Al(B5O10)] · 4H2O and (NH4)2 [Al(B5O10)] · 4H2O The Journal of Chemical Thermodynamics. ,vol. 58, pp. 129- 133 ,(2013) , 10.1016/J.JCT.2012.11.003
Petra Becker, Borate Materials in Nonlinear Optics Advanced Materials. ,vol. 10, pp. 979- 992 ,(1998) , 10.1002/(SICI)1521-4095(199809)10:13<979::AID-ADMA979>3.0.CO;2-N
Zhi-Hong Liu, Ping Li, Chuan-Feng Zuo, Standard Molar Enthalpies of Formation for the Two Hydrated Calcium Borates xCaO·5B2O3·yH2O (x = 2 and 4, y = 5 and 7) Journal of Chemical & Engineering Data. ,vol. 51, pp. 272- 275 ,(2006) , 10.1021/JE050383M