Preparation of cathode materials for Li-ion cells by acid dissolution

作者: Si Hyoung Oh , Woon Tae Jeong , Won Il Cho , Byung Won Cho , Kyoungja Woo

DOI: 10.1016/J.JALLCOM.2004.08.082

关键词: Transition metalCobalt hydroxideSolventAcrylic acidInorganic chemistryElectrochemistryMaterials scienceLithiumCalcinationCobalt

摘要: Abstract New synthesis route called acid dissolution method, preparing the high-performance cathode materials for lithium-ion cells, was successfully developed. In this insoluble starting such as metal carbonates or hydroxides are dissolved in strong organic acidic solution which contains a chelating agent. And then, solvent of containing is eliminated to obtain xerogel initial whose chemical form expressed Li[MA 3 ], where M transition atom and A anion acid. The then calcined at high temperature polycrystalline materials. work, applicability method demonstrated synthesizing single-phase LiCoO 2 using lithium carbonate, cobalt hydroxide acrylic synthesized powders 800 °C showed good electrochemical performance half-cell test.

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