作者: Y. Akama , M. Shiro , T. Ueda , M. Kajitani
DOI: 10.1107/S0108270194007389
关键词: Molecule 、 Chemistry 、 Enol 、 Conformational isomerism 、 Intramolecular force 、 Pyrazolone 、 Stereochemistry 、 Hydrogen bond 、 Enone 、 Tautomer
摘要: The tautomeric keto and enol forms of 4-benzoyl-3-methyl-1-phenyl-5(2H)-pyrazolone, C 17 H 14 N 2 O , have been prepared their crystal structures characterized by X-ray analysis. unit cell the form, 4-benzoyl-5-hydroxy-3-methyl-1-phenylpyrazole, contains two structural conformers. intramolecular distances in form [2.621(3) 2.663 (2) A] indicate presence hydrogen bonds, while corresponding distance [3.079 (3) does not. In there is an intermolecular bond [2.673(3) between imino N(2) atom carbonyl O(1) atom.