Torsion-Rotation Energy Levels, Hindering Potential, and Inertial Parameters of the First Excited Vibrational State of the Antisymmetric O-H Stretch in Hydrogen Peroxide
作者： W.B. Cook , R.H. Hunt , W.N. Shelton , F.A. Flaherty
关键词: Antisymmetric relation 、 Torsion (mechanics) 、 Inertial frame of reference 、 Hamiltonian (quantum mechanics) 、 Atomic physics 、 Hydrogen peroxide 、 Fourier transform spectra 、 Physics 、 Excited state
摘要: Abstract Torsion-rotation energy levels of the excited vibrational state antisymmetric OH-stretch fundamental ν 5 hydrogen peroxide are reported. These determined from 1.24 m path difference Fourier transform spectra taken between 3200 and 4200 cm −1 analyzed in conjunction with published ground levels. The results include torsional states n = 0, 1, 2. Many perturbed. An analysis these for J K A fit experimental a one-dimensional Hamiltonian gives trans barrier height 429 cis about 2500 .
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