The Infra-Red Spectra of Polymers and Related Monomers. II

作者:

DOI: 10.1098/RSPA.1943.0036

关键词: MonomerVinyl chloridePolyvinylidene chlorideVinyl bromidePhysical chemistryChemistryPhotochemistryPolyvinyl chlorideBromideChlorideHalide

摘要: The infra-red spectra of some polymers containing chlorine have been measured, and also those the related monomers. Vibrational analyses a study band contours with vinyl chloride, bromide, vinylidene made it possible to assign magnitudes many normal vibration frequencies. frequencies series halides correlated. rotational structure associated bands has discussed in relation molecular structure. Similar measurements considerations applied chloroprene. polyvinyl polyvinylidene halothenes neoprenes examined. As preliminary correlation absorption vibrations nuclear skeletons, simple chlorinated paraffins measured.

参考文章(7)
K. W. F. Kohlrausch, Der Smekal-Raman-Effekt: Ergänzungsband 1931–1937 Springer Berlin Heidelberg. ,(1938) , 10.1007/978-3-642-90675-6
H. W. Melville, Some themes in the chemistry of macromolecules Journal of The Chemical Society (resumed). pp. 414- 426 ,(1941) , 10.1039/JR9410000414
Dudley Williams, An Application of Infrared Spectroscopy to Rubber Chemistry Physics. ,vol. 7, pp. 399- 402 ,(1936) , 10.1063/1.1745348
Sherman L. Gerhard, David M. Dennison, The Envelopes of Infrared Absorption Bands Physical Review. ,vol. 43, pp. 197- 204 ,(1933) , 10.1103/PHYSREV.43.197
W. H. Avery, C. F. Ellis, Infra‐Red Spectra of Hydrocarbons I. Some Investigations of the Temperature Dependence of Absorption Bands The Journal of Chemical Physics. ,vol. 10, pp. 10- 18 ,(1942) , 10.1063/1.1723615
Jean Cabannes, Sur l'isomerie cis et trans Journal of Computers. ,vol. 35, pp. 1- 15 ,(1938) , 10.1051/JCP/1938350001