Production and utilization performance of a glycerol derived additive for diesel engines

作者: Diana Hernández , Jhon J. Fernández , Fanor Mondragón , Diana López

DOI: 10.1016/J.FUEL.2011.06.073

关键词: Organic chemistryDiesel fuelCatalysisPour pointBiomassDiesel engineGlycerolCombustionChemistryDecomposition

摘要: Abstract Oxygenated additives have been the subject of much research because they notably improve fuel characteristics and combustion performance. Moreover, there is a tendency to use oxygenated derived from biomass. In case glycerol, previous studies shown that compounds are generated by dehydration, decomposition isomerization reactions glycerol its intermediaries, where selected route these depends on type catalyst used. this work, liquid phase obtained during catalytic at 400 °C using basic was characterized GC GC–MS. This constituted mostly highly known energetic use. After drying process, effect condensates as an additive in diesel–biodiesel (B5) engines 0.2% (v/v) concentration evaluated. The physical properties mechanic, thermodynamic, environmental performance stationary diesel engine were analyzed current study. presence decreased pour point amount particulate matter combustion.

参考文章(21)
Hu Chen, Jianxin Wang, Shijin Shuai, Wenmiao Chen, Study of oxygenated biomass fuel blends on a diesel engine Fuel. ,vol. 87, pp. 3462- 3468 ,(2008) , 10.1016/J.FUEL.2008.04.034
Germán Sierra Gallego, Catherine Batiot-Dupeyrat, Joël Barrault, Elizabeth Florez, Fanor Mondragón, Dry reforming of methane over LaNi1-yByO3±δ (B = Mg, Co) perovskites used as catalyst precursor Applied Catalysis A-general. ,vol. 334, pp. 251- 258 ,(2008) , 10.1016/J.APCATA.2007.10.010
Magín Lapuerta, Octavio Armas, Reyes García-Contreras, Effect of Ethanol on Blending Stability and Diesel Engine Emissions Energy & Fuels. ,vol. 23, pp. 4343- 4354 ,(2009) , 10.1021/EF900448M
Claudio J. A. Mota, Carolina X. A. da Silva, Nilton Rosenbach, Jair Costa, Flávia da Silva, Glycerin Derivatives as Fuel Additives: The Addition of Glycerol/Acetone Ketal (Solketal) in Gasolines Energy & Fuels. ,vol. 24, pp. 2733- 2736 ,(2010) , 10.1021/EF9015735
J.Thomas Mckinnon, Eleanor Meyer, Jack B Howard, Infrared analysis of flame-generated PAH samples Combustion and Flame. ,vol. 105, pp. 161- 166 ,(1996) , 10.1016/0010-2180(95)00185-9
Germán Sierra Gallego, Joël Barrault, Catherine Batiot-Dupeyrat, Fanor Mondragón, Production of hydrogen and MWCNTs by methane decomposition over catalysts originated from LaNiO3 perovskite Catalysis Today. ,vol. 149, pp. 365- 371 ,(2010) , 10.1016/J.CATTOD.2009.06.004
Wladimir Suprun, Michal Lutecki, Thomas Haber, Helmut Papp, Acidic catalysts for the dehydration of glycerol: Activity and deactivation Journal of Molecular Catalysis A-chemical. ,vol. 309, pp. 71- 78 ,(2009) , 10.1016/J.MOLCATA.2009.04.017
Satoshi Sato, Ryoji Takahashi, Mika Kobune, Hirotomo Inoue, Yusuke Izawa, Hironobu Ohno, Kazunari Takahashi, Dehydration of 1,4-butanediol over rare earth oxides Applied Catalysis A-general. ,vol. 356, pp. 64- 71 ,(2009) , 10.1016/J.APCATA.2008.12.017
Eva García, Miriam Laca, Elena Pérez, Angel Garrido, Julián Peinado, New Class of Acetal Derived from Glycerin as a Biodiesel Fuel Component Energy & Fuels. ,vol. 22, pp. 4274- 4280 ,(2008) , 10.1021/EF800477M
Paulo H.R. Silva, Valter L.C. Gonçalves, Claudio J.A. Mota, Glycerol acetals as anti-freezing additives for biodiesel. Bioresource Technology. ,vol. 101, pp. 6225- 6229 ,(2010) , 10.1016/J.BIORTECH.2010.02.101