Nanoprecipitation in Quartz Nanopipettes and Application in the Crystallization of Inorganic Salts
作者： Warren D Brown
DOI:
关键词: Materials science 、 Crystallization 、 Surface-area-to-volume ratio 、 Electrochemistry 、 Nanotechnology 、 Ionic bonding 、 Lithium chloride 、 Nanopore 、 Biomolecule 、 Chemical engineering 、 Electrolyte
摘要: The high surface to volume ratio which is a property of nanoscale devices means the interfacial effects from these on mass transport analyte can be significant. Quartz nanopipette effect behavior inorganic monovalent salts such as potassium chloride shown differ those conical nanopore. nanopipettes demonstrate more significant impact salts. This evidenced by impacts ionic even at electrolyte concentration where nanopore do not significantly ion transport. Nanopipettes have been use precipitate lithium in bulk concentrations three orders magnitude below saturation concentration. These novel interactions opened new avenues for crystallization complex organic biomolecules using systems model base approach systems. INDEX WORDS: Nanoprecipitation, Crystallization, Ionic Transport, Mass Nanodevices, Nanopipette, Nanopores, Current rectification, Electrochemistry NANOPRECIPITATION IN QUARTZ NANOPIPETTES AND APPLICATION THE CRYSTALLIZATION OF INORGANIC SALTS
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