Composites of Donor-π-Acceptor type configured organic compound and porous ZnO nano sheets as corrosion inhibitors of copper in chloride environment
作者： Gopal Ji , Rajiv Prakash , None
DOI: 10.1016/J.MOLLIQ.2019.02.026
关键词: Corrosion 、 Electrochemistry 、 Calcination 、 Copper 、 Langmuir 、 Composite material 、 Adsorption 、 Chloride 、 High-resolution transmission electron microscopy 、 Materials science
摘要: Abstract Donor-π-Acceptor (D-π-A) type compounds are very interesting for corrosion study since they have unique structural configuration. Their high chemical reactivity promotes an easy bonding with the metals, which helps in inhibition. In this work, ethyl-2-cyano-3-(4-(dimethylamino) phenyl) acrylate (ECDPA) (a D-π-A compound) is used to restrict copper loss 1 M HCl. The impedance analysis portrays that ECDPA saves 75% of at its maximum concentration HCl solution. To further increase inhibition efficiency, ECDPA-ZnO composites developed. ZnO synthesized hydrothermally and calcined two different temperatures (300 °C 500 °C). morphology changes drastically calcination; however, main morphological difference 300 °C (Z3) 500 °C (Z5) increment porosity. Hence, made analyze change behavior composites. designated as: EZ3 EZ5. characterizations ZnO, been performed by UV–visible spectroscopy, FTIR HRTEM, HRSEM, EDAX XRD techniques. efficiencies EZ5 achieved as 78% 81%. This fact suggests increases adsorption over surface, confirmed Langmuir electrochemical atomic force microscopy (EC-AFM) measurements.
sci-hub.se 参考文章(46)
Huiwen Tian, Y. Frank Cheng, Weihua Li, Baorong Hou, Triazolyl-acylhydrazone derivatives as novel inhibitors for copper corrosion in chloride solutions Corrosion Science. ,vol. 100, pp. 341- 352 ,(2015) , 10.1016/J.CORSCI.2015.08.022
Martina Levin, Per Wiklund, Christofer Leygraf, Bioorganic compounds as copper corrosion inhibitors in hydrocarbon media Corrosion Science. ,vol. 58, pp. 104- 114 ,(2012) , 10.1016/J.CORSCI.2012.01.009
Song Hong, Wen Chen, Hong Qun Luo, Nian Bing Li, Inhibition effect of 4-amino-antipyrine on the corrosion of copper in 3 wt.% NaCl solution Corrosion Science. ,vol. 57, pp. 270- 278 ,(2012) , 10.1016/J.CORSCI.2011.12.009
Miriam S Tokumoto, Sandra H Pulcinelli, Celso V Santilli, Valérie Briois, None, Catalysis and temperature dependence on the formation of ZnO nanoparticles and of zinc acetate derivatives prepared by the sol-gel route Journal of Physical Chemistry B. ,vol. 107, pp. 568- 574 ,(2004) , 10.1021/JP0217381
Lin Guo, Shihe Yang, Chunlei Yang, Ping Yu, Jiannong Wang, Weikun Ge, George K. L. Wong, Highly monodisperse polymer-capped ZnO nanoparticles: Preparation and optical properties Applied Physics Letters. ,vol. 76, pp. 2901- 2903 ,(2000) , 10.1063/1.126511
Xiaoyan Qin, Xiaoyang Zhang, Ying Dai, Junpeng Wang, Zeyan Wang, Baibiao Huang, Yandong Ma, Yuanyuan Liu, Oxygen vacancy induced band-gap narrowing and enhanced visible light photocatalytic activity of ZnO. ACS Applied Materials & Interfaces. ,vol. 4, pp. 4024- 4030 ,(2012) , 10.1021/AM300835P
G. Lewis, The corrosion inhibition of copper by benzimidazole Corrosion Science. ,vol. 22, pp. 579- 584 ,(1982) , 10.1016/0010-938X(82)90056-7
G Bertrand, E Rocca, C Savall, C Rapin, J.-C Labrune, P Steinmetz, In-situ electrochemical atomic force microscopy studies of aqueous corrosion and inhibition of copper Journal of Electroanalytical Chemistry. ,vol. 489, pp. 38- 45 ,(2000) , 10.1016/S0022-0728(00)00163-7
Da-Quan Zhang, Bin Xie, Li-Xin Gao, Qi-Rui Cai, Hyung Goun Joo, Kang Yong Lee, Intramolecular synergistic effect of glutamic acid, cysteine and glycine against copper corrosion in hydrochloric acid solution Thin Solid Films. ,vol. 520, pp. 356- 361 ,(2011) , 10.1016/J.TSF.2011.07.009
Zhang, K. Yanagisawa, Hydrothermal Synthesis of Zinc Hydroxide Chloride Sheets and Their Conversion to ZnO Chemistry of Materials. ,vol. 19, pp. 2329- 2334 ,(2007) , 10.1021/CM0626841