Substituenteneffekte in den 13C‐NMR‐Spektren von diastereomeren Chalkondihalogeniden. V. Synthese, Stereochemie und Spektroskopie von Chalkonfluorhydrinen

作者: Fritz Gerd Weber , Hartmut Giese , Hubert Köppel , Monika Reinhold , Rita Strobel

DOI: 10.1002/PRAC.19853270120

关键词: ChalconeStereochemistryDiastereomerSpectroscopySubstituentChlorohydrinsVicinalChemistry

摘要: Substituent Effects in 13C- N. M. R. Spectra of Diastereomeric Chalcone Dihalogenides. V. Synthesis, Stereochemistry and Spectroscopy Fluorohydrines Chalcone fluorohydrins 1 diastereomeric pairs chalcone chlorohydrins 2 as standards are investigated the i.r., 1H, 19F, 13C n m. r. spectroscopy field. The substituent dependence spectral parameters is discussed. The assignment conformation configuration on basis vicinal 1H1H, 1H19F, 1H13C coupling constants determined.

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