A combined experimental and theoretical study on diglyme + 1-alkanol liquid mixtures
作者： M. Atilhan , J.L. Trenzado , S. Aparicio , S. Rozas , M.N. Caro
DOI: 10.1016/J.MOLLIQ.2021.116048
关键词: Diglyme 、 Hydrogen bond 、 Ether 、 Molecular simulation 、 Characterization (materials science) 、 Materials science 、 Intermolecular force 、 Thermodynamics
摘要: Abstract The properties, structuring and intermolecular forces of diglyme + alkanol mixtures are studied using a combined experimental theoretical approach. thermophysical properties as well the molecular simulation results provide detailed characterization in terms composition, type 1-alkanol temperature. possibility development heteroassociations by glyme - hydrogen bonding their effect on weakening breaking alkanols self-association show pivotal role structure self-association. reported complex structural effects varying with composition which may be considered model ether – hydroxyl interaction mixture’s nature.
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