Apparent Molar Volumes and Adiabatic Compressibilities of Crown Ethers and Glymes in H2O and D2O at 25°C
作者： Pedro Bernal , Jennifer McCluan
关键词: 15-Crown-5 、 Chemistry 、 Aqueous solution 、 Molar volume 、 Kinetic isotope effect 、 Molar 、 18-Crown-6 、 Thermodynamics 、 Ether 、 Solvent 、 Organic chemistry
摘要: The apparent molar volumes and adiabatic compressibilities of 18-Crown-6, 15-Crown-5, 12-Crown-4, tetraglyme, triglyme were measured at 25°C in H2O D2O. contribution the -CH2CH2O- group to limiting partial cyclic open-chain ethers both solvents are compared solvent isotope effects calculated. It is concluded, based on compressibility results, that there a subtle difference between hydration ethene oxde this persists These results indicate calculation using additivity schemes will have account for whether or compound.
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